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Novel synthesis of Planococcus citri pheromone
Authors:O S Kukovinets  T I Zvereva  V G Kasradze  F Z Galin  L L Frolova  A V Kuchin  L V Spirikhin  M I Abdullin
Institution:(1) Bashkir State University, 450014 Ufa, 14, Mingazheva, 100;(2) Institute of Organic Chemistry, Urals Scientific Center, Russian Academy of Sciences, 450054 Ufa, 54, pr. Oktyabrya, 71;(3) Institute of Chemistry, Komi Scientific Center, Urals Division, Russian Academy of Sciences, 167982 Syktyvkar, Komi, Pervomaiskaya, 48
Abstract:An effective method was proposed for synthesizing (+)-cis-1R-acetoxymethyl-3-isopropenyl-2,2-dimethylcyclobutane, a pheromone of the citrus mealybug, based on ozonolysis of verbenone that led in one step to the key synthon 1R,3S-3-acetyl-2,2-dimethylcyclobutanecarboxylic acid. __________ Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 179–180, March–April, 2006.
Keywords:pheromone  citrus mealybug  olefination  ozonolysis
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