惰性化学键活化与重组

惰性化学键的活化与重组是近几年来非常热门的研究领域, 同时这个领域也非常富有挑战性. 本文以麻生明教授为首席的国家重点基础研究发展项目（973项目）“惰性化学键的选择性激活、重组及其控制”为基础, 阐述了惰性碳-杂原子键, 碳-氢键, 碳-碳键, 二氧化碳和氧气小分子四个方面的活化和重组, 介绍了一些催化合成的新方法. 这些新方法在完成惰性化学键活化和重组的同时, 也注重于降低污染, 使用更温和的条件, 提高了原子经济性, 为可持续发展战略提供了强有力的技术支持.

Activation and controlled transformation of inactive chemical bonds

The activation and controlled transformation of inactive chemical bonds is extremely attractive topic, and is also one of the most challenging areas in chemical research. Based on the National Basic Research Program of China （973 Project, 2009CB825300） leaded by Prof. Shengming Ma, which focuses on the activation and controlled transformation of C-X bonds, C-H bonds, C-C bonds and small molecules such as carbon dioxide and oxygen. Some recent methodologies developed by this program are introduced in this paper. These new methods not only achieve the activation and controlled transformation of inert chemical bonds, but also focus on terms of reducing environmental pollution, using milder conditions and improving atomic economy. The developed novel methodologies would provide solid support for the strategy of sustainable development.