| 二安替比林对甲氧基苯基甲烷与锰(Ⅳ)的高选择性显色反应研究及应用 |
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| 引用本文： | 黄章杰,杨光宇,尹家元,徐其亨.二安替比林对甲氧基苯基甲烷与锰(Ⅳ)的高选择性显色反应研究及应用[J].分析科学学报,1999(3). |
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| 作者姓名： | 黄章杰 杨光宇 尹家元 徐其亨 |
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| 作者单位： | 云南大学科研处，云南大学化学系 |
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| 摘 要： | 在碱性介质中，空气氧化Ｍｎ（Ⅱ）为Ｍｎ（Ⅳ），然后在酸性介质中，Ｍｎ（Ⅳ）氧化二安替比林对甲氧基苯基甲烷（ＤＡｐＭＭ）生成黄色产物，λｍａｘ＝４５０ｎｍ，ε＝５．４５×１０４Ｌ·ｍｏｌ－１·ｃｍ－１。锰含量在０～２０μｇ／２５ｍＬ内符合比尔定律。方法用于钢样中锰的测定，结果满意
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| 关 键 词： | 二安替比林对甲氧基苯基甲烷 分光光度法 锰 |
A High Selective Color Reaction of Manganese with \=Diantipyryl\|(p\|methoxy)\|phenylmethane \=and Its Application |
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| Huang Zhangjie,Yang Guangyu,Yin Jiayuan,Xu Qiheng\.A High Selective Color Reaction of Manganese with \=Diantipyryl\|(p\|methoxy)\|phenylmethane \=and Its Application[J].Journal of Analytical Science,1999(3). |
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| Authors: | Huang Zhangjie Yang Guangyu Yin Jiayuan Xu Qiheng\ |
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| Institution: | Huang Zhangjie,Yang Guangyu,Yin Jiayuan,Xu Qiheng\+ * |
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| Abstract: | In the alkaline medium, manganese()was oxidized to manganese() by air. In the phosphoric acid medium, manganese() reacts with diantipyryl\|(p\|methoxy)\|phenylmethane(DApMM) to form a yellow product. The molar absorptivity is 5.4510\+4 Lmol\+\{-1\}cm\+\{-1\} at 450 nm. Beers law is obeyed in the range of 020 g/25mL. This method can be applied to the determination of manganese in steel with satisfactory result. |
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| Keywords: | Diantipyryl(pmethoxy)phenylmethane Manganese Spectrophotometry |
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