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分层性物质的组合取样误差与份样数目之间的关系及其Monte Carlo模拟
引用本文:高志,何锡文,李一峻.分层性物质的组合取样误差与份样数目之间的关系及其Monte Carlo模拟[J].分析科学学报,1999(5).
作者姓名:高志  何锡文  李一峻
作者单位:南开大学化学系!天津,300071,南开大学化学系!天津,300071,南开大学化学系!天津,300071
摘    要:本文从理论上研究了分层性物质的组合取样误差与份样数目之间的定量关系,表明份样数目与组合取样相对标准偏差的平方之积为一常数,称为组合取样常数,它与Ingam ells 和Sw itzer 提出的取样常数是相似的,表示68% 置信度下组合取样的相对标准偏差达到1% 时的份样数目。应用Monte Carlo 模拟技术对该理论进行了验证,结果令人满意。

关 键 词:分层性物质  组合取样常数  取样误差  MonteCarlo模拟

Investigation on the Relationship between Composite Sampling Error and the Number of Increments for Chemical Analysis of Stratified Materials with Monte Carlo Simulation Technique
Gao Zhi,He Xiwen ,Li Yijun.Investigation on the Relationship between Composite Sampling Error and the Number of Increments for Chemical Analysis of Stratified Materials with Monte Carlo Simulation Technique[J].Journal of Analytical Science,1999(5).
Authors:Gao Zhi  He Xiwen  Li Yijun
Institution:Gao Zhi,He Xiwen *,Li Yijun
Abstract:The theoretical study was carried out for the relationship between composite sampling error and the number of the increments for chemical analysis of stratified materials. It reveals that the product of the number of increments and the square of the relative standard sampling deviation is a constant, which is named as the composite sampling constant. Monte Carlo simulation technique was used to testify the above theory. The stratified populations studied in this paper were Gaussian , uniform random and multi nomial (taking silicon carbide material as an example) distributions. The results were found to be similar for the different populations.
Keywords:Stratified population  Composite sampling constant  Sampling error    Monte Carlo simulation
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