| 用高分辨质谱研究二茂铁类化合物 |
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| 引用本文： | 赵媛媛,景治中.用高分辨质谱研究二茂铁类化合物[J].分析科学学报,2002,18(6):466-468. |
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| 作者姓名： | 赵媛媛 景治中 |
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| 作者单位： | 武汉大学化学与分子科学学院,武汉,430072 |
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| 摘 要： | 研究了八种N－二茂铁甲基苯胺衍生物的电子电离质谱（EI－MS），并与快原子轰击质谱（FAB－MS）作了比较，讨论了这些化合物的质谱特征。通过精确质量测量，确认了M^ -2 OH离子，并采用碰撞诱导裂解（CID）探讨了化合物质谱中主要离子间的关系。
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| 关 键 词： | 二茂铁类化合物 EI FAB CID 高分辩质谱 N－二茂铁甲基苯胺 |
| 文章编号： | 1006-6144(2002)06-0466-03 |
| 修稿时间： | 2002年3月5日 |
High Resolving Mass Spectra of Compounds Containing Ferrocenyl |
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| ZHAO Yuan-yuan,JING Zhi-zhong.High Resolving Mass Spectra of Compounds Containing Ferrocenyl[J].Journal of Analytical Science,2002,18(6):466-468. |
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| Authors: | ZHAO Yuan-yuan JING Zhi-zhong |
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| Institution: | ZHAO Yuan-yuan,JING Zhi-zhong * |
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| Abstract: | In this paper, the electron ionization (EI) mass spectra of N-ferrocenylmethylaniline derivatives were studied. By comparing with their fast atom-bombardment (FAB-MS), we discussed the MS characteristics of these compounds. Ions M +-2OH were identified by peak matching methods. In addition, the relationships of fragment ions were further demonstrated by collision induced dissociation (CID). |
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| Keywords: | Ferrocenyl EI FAB CID High resolving mass spectra |
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