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| 十二烷基硫酸钠微乳色谱体系中pH值对其电渗流行为与微结构的影响 | |
| 引用本文： | 程宏英,刘家辉,叶进,屠一锋.十二烷基硫酸钠微乳色谱体系中pH值对其电渗流行为与微结构的影响[J].分析科学学报,2011,27(5):595-598. |
| 作者姓名： | 程宏英 刘家辉 叶进 屠一锋 |
| 作者单位： | 1. 苏州大学材料与化学工程学部,江苏苏州215123;苏州科技学院化学与生物工程学院,江苏苏州215009 2. 苏州科技学院化学与生物工程学院,江苏苏州,215009 3. 苏州大学材料与化学工程学部,江苏苏州,215123 |
| 基金项目： | 江苏省高校自然科学基金(No.08KJD150006) |
| 摘 要： | 以十二烷基硫酸钠(SDS)/正己烷/正丁醇/硼砂微乳液为毛细管电色谱运行研究体系,以甲醇峰为微乳体系电渗流峰(EOF),考察不同pH值条件下微乳体系电渗流出峰时间(tEOF)和变化趋势.以微乳液滴粒径和ξ电位考察pH值对SDS缓冲溶液微乳体系微结构的影响,用微乳体系的电导值分析pH值条件下微乳液滴与氢氧根离子之间的相互... |
| 关 键 词： | 十二烷基硫酸钠 微乳液 微乳微结构 电渗流 |
The Effect of pH Value on Electroosmotic Flow Behavior and Microstructures in the Sodium Dodecyl Sulfate Microemulsion Chromatography System |
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| CHENG Hong-ying,LIU Jia-hui,YE Jin,TU Yi-feng.The Effect of pH Value on Electroosmotic Flow Behavior and Microstructures in the Sodium Dodecyl Sulfate Microemulsion Chromatography System[J].Journal of Analytical Science,2011,27(5):595-598. | |
| Authors: | CHENG Hong-ying LIU Jia-hui YE Jin TU Yi-feng |
| Institution: | CHENG Hong-ying1,2,LIU Jia-hui 2,YE Jin 2,TU Yi-feng*1(1.Institute of Analytical Chemistry,Department of Chemistry,Dushu Lake Campus Suzhou University,Suzhou 215123,2.Department of Chemistry,Suzhou University of Science and Technology,Suzhou 215009) |
| Abstract: | With sodium dodecyl sulfate(SDS)/n-hexane/n-butanol/tetraborate microemulsion as running buffer in capillary electrophoresis chromatography,the variation of electroosmotic flow(EOF) in different pH conditions have been discussed with the methanol peak as the EOF in this microemulsion system.The effect of pH value on the microstructure of the microemulsion system by determining particle sizes and zeta potential of microdroplets was studied,and effect of pH value on the interaction between micro droplets was ... |
| Keywords: | Sodium dodecyl sulfate Electroosmotic flow Microemulsion Microstructure |
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