| 红外光谱法对六氟磷酸锂的快速定量分析 |
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| 引用本文： | 肖跃龙,戴璇,张翼,徐行,刘洪涛,潘春跃.红外光谱法对六氟磷酸锂的快速定量分析[J].分析科学学报,2012,28(3):357-360. |
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| 作者姓名： | 肖跃龙 戴璇 张翼 徐行 刘洪涛 潘春跃 |
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| 作者单位： | 中南大学化学化工学院,湖南长沙,410083 |
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| 基金项目： | 国家自然科学基金，湖南有色集团-中南大学有色金属研究基金 |
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| 摘 要： | 本文建立了一种用傅里叶红外光谱(FT-IR)法快速定量分析LiPF6的方法。采用红外光谱(IR)法和X射线衍射(XRD)法对LiPF6样品进行了定性分析。选取LiPF6红外光谱847cm-1处的特征吸收峰为分析对象,利用吸光度峰面积积分法进行定量分析,由标准曲线可知,LiPF6的含量与其红外光谱特征峰的吸收强度有很好的线性关系,相关系数达0.9998,线性范围在0.04～25mg.mL-1,检出限可达0.02mg.mL-1。LiPF6样品定量测定的相对标准偏差(RSD)约为0.18%,回收率为96%～98%。
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| 关 键 词： | 红外光谱法 六氟磷酸锂 定量分析 X射线衍射法 |
Rapid Quantitative Analysis of Lithium Hexafluorophosphate by Infrared Spectroscopy |
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| XIAO Yue-long
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DAI Xuan
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ZHANG Yi
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XU Hang
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LIU Hong-tao
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PAN Chun-yue.Rapid Quantitative Analysis of Lithium Hexafluorophosphate by Infrared Spectroscopy[J].Journal of Analytical Science,2012,28(3):357-360. |
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| Authors: | XIAO Yue-long DAI Xuan ZHANG Yi XU Hang LIU Hong-tao PAN Chun-yue |
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| Institution: | (School of Chemistry and Chemical Engineering,Central South University,Changsha410083) |
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| Abstract: | A quantitative analysis method for the determination of lithium hexafluorophosphate(LiPF6) by infrared spectroscopy was developed.The infrared(IR)and X-ray diffraction(XRD)methods were used for qualitative analysis of the sample of LiPF6.It was found that the integrated peak area of the absorption peak of LiPF6at 847cm-1 increased linearly with the content of LiPF6 with a correlation coefficient of 0.9998,the linear range was 0.04～25mg.mL-1,and the detection limit was 0.02mg.mL-1.The recovery range of this method was 96%～98%. |
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| Keywords: | Infrared spectroscopy Lithium hexafluorophosphate Quantitative analysis X-ray diffraction |
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