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| 二(1-环戊烯基茚基)四羰基二钌的合成、晶体结构及热稳定性研究 | |
| 引用本文： | 郭凯明,马志宏,李素贞,韩占刚,林 进,郑学忠.二(1-环戊烯基茚基)四羰基二钌的合成、晶体结构及热稳定性研究[J].无机化学学报,2012,28(3):643-646. |
| 作者姓名： | 郭凯明 马志宏 李素贞 韩占刚 林 进 郑学忠 |
| 作者单位： | 1. 河北师范大学化学与材料科学学院,石家庄,050016 2. 河北医科大学基础医学院,石家庄,050017 3. 河北工业职业技术学院,石家庄,050091 |
| 基金项目： | 河北师范大学重点基金(No.L2009Z06);河北省自然科学基金(No.B2011205035)资助项目 |
| 摘 要： | 由6,6-四亚甲基苯并富烯C9H6C(CH2)4与Ru3(CO)12在二甲苯中加热回流,合成了一个钌配合物((η5-C9H6)C(C4H7))2Ru2(μ-CO)2(CO)2]。通过元素分析、红外、热重、核磁共振进行了表征及研究。用X射线单晶衍射法测定了((η5-C9H6)C(C4H7))2Ru2(μ-CO)2(CO)2]的结构,结果表明:晶体属于单斜晶系,P21/c空间群,a=0.757 1(13)nm,b=1.577 7(3)nm,c=1.107 3(19)nm,β=90.07(2)°,V=1.322 6(4)nm3,Dc=1.699 g.cm-3,μ=1.179 mm-1,F(000)=676,Z=2,R1=0.030 5,wR2=0.072 4。 |
| 关 键 词： | 羰基钌 茚基 晶体结构 X-射线衍射 |
Synthesis, Crystal Structure and Thermal Stability of Di(1-cyclopentenylindenyl) Tetracarbonyl Diruthenium |
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| GUO Kai-Ming,MA Zhi-Hong,LI Su-Zhen,HAN Zhan-Gang,LIN Jin and ZHENG Xue-Zhong.Synthesis, Crystal Structure and Thermal Stability of Di(1-cyclopentenylindenyl) Tetracarbonyl Diruthenium[J].Chinese Journal of Inorganic Chemistry,2012,28(3):643-646. | |
| Authors: | GUO Kai-Ming MA Zhi-Hong LI Su-Zhen HAN Zhan-Gang LIN Jin and ZHENG Xue-Zhong |
| Institution: | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China,College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China,Hebei College of Industry and Technology, Shijiazhuang 050091, China,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China and College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China |
| Abstract: | A ruthenium complex ((η5-C9H6)C(C4H7))2Ru2(μ-CO)2(CO)2] was synthesized by the reaction of 6,6-tetramethylenebenzofulvene C9H6C(CH2)4 with Ru3(CO)12 in refluxing xylene,and characterized by elemental analysis,IR,TG,1H NMR spectra and X-ray diffraction.Crystal data for this compound: monoclinic,space group P21/c,a=0.757 1(13) nm,b=1.577 7(3) nm,c=1.107 3(19) nm,β=90.07(2)°,V=1.322 6(4) nm3,Dc=1.699 g·cm-3,μ=1.179 mm-1,F(000)=676,Z=2,R1=0.030 5,wR2=0.072 4.CCDC: 805628. |
| Keywords: | ruthenium carbonyl indenyl crystal structure X-ray diffraction |
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