| 芳酰腙配体与Ni(Ⅱ)和Co(Ⅱ)配合物的水热合成与晶体结构 |
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| 引用本文： | 郑长征,王 亮,刘 娟.芳酰腙配体与Ni(Ⅱ)和Co(Ⅱ)配合物的水热合成与晶体结构[J].无机化学学报,2012,28(3):637-642. |
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| 作者姓名： | 郑长征 王 亮 刘 娟 |
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| 作者单位： | 西安工程大学环境与化学工程学院,西安,710048 |
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| 基金项目： | 陕西省自然科学基金(No.2009JM2012)资助项目 |
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| 摘 要： | 由苯亚甲基苯乙酮和苯甲酰肼合成一种新型双齿(O、N)酰腙配体(苯亚甲基苯乙酮苯甲酰腙)。由水热法合成了两种配合物M(babh)2(py)2](M=Ni,1;Co,2;Hbabh=苯亚甲基苯乙酮苯甲酰腙,py=吡啶),并用元素分析、红外、热重及X-射线单晶衍射对其进行了表征。晶体结构分析结果表明:两个化合物均属单斜晶系,空间群均是P21/n。化合物1和2通过分子间弱的C-H…π堆积形成二维片状超分子层。
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| 关 键 词： | 席夫碱 酰腙配体 水热合成 配合物 晶体结构 |
Hydrothermal Synthesis and Crystal Structure of Ni(Ⅱ) and Co(Ⅱ) Complexes with Hydrazone Ligand |
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| ZHENG Chang-Zheng,WANG Liang and LIU Juan.Hydrothermal Synthesis and Crystal Structure of Ni(Ⅱ) and Co(Ⅱ) Complexes with Hydrazone Ligand[J].Chinese Journal of Inorganic Chemistry,2012,28(3):637-642. |
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| Authors: | ZHENG Chang-Zheng WANG Liang and LIU Juan |
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| Institution: | ZHENG Chang-Zheng WANG Liang LIU Juan(School of Environmental and Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China) |
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| Abstract: | A new bidentate ON hydrazone ligand,has been designed and synthesized by benzylidene acetophenone with benzoyl hydrazine(Hbabh).Two coordination compounds,namely M(babh)2(py)2](M=Ni,1;Co,2;Hbabh=benzylidene acetophenone benzoyl hydrazone,py=pyridine),have been hydrothermally synthesized and characterized by analytical,IR,TG analysis and single-crystal X-ray diffraction measurements.The two compounds crystallize in the Monoclinic space group P21/n.A view of 2D sheet structure in 1 and 2 are packed alongside with each other through weak C-H…π interactions.CCDC: 819582,1;819583,2. |
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| Keywords: | Schiff base hydrazone ligand hydrothermal synthesis complexes crystal structure |
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