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金修饰ZnO纳米棒阵列制备及对甲醛气敏性能
引用本文:陈伟良,尹 静,黄春舒,王学伟,袁志好,别利剑.金修饰ZnO纳米棒阵列制备及对甲醛气敏性能[J].无机化学学报,2010,26(4):586-590.
作者姓名:陈伟良  尹 静  黄春舒  王学伟  袁志好  别利剑
作者单位:1. 天津理工大学材料科学与工程学院纳米材料与技术研究中心,天津,300384
2. 天津理工大学环境科学与安全工程学院,天津,300384
3. 天津理工大学材料科学与工程学院纳米材料与技术研究中心,天津,300384;显示材料与光电器件省部共建教育部重点实验室,天津,300384
基金项目:天津市自然科学基金项目,天津市高等学校科技发展基金项目,天津市"材料物理与化学"重点学科资助 
摘    要:通过两步溶液法在氧化铝陶瓷管上先制备出ZnO纳米棒阵列,再用真空蒸镀法在ZnO纳米棒表面形成一层均匀Au膜,于500℃下热处理得到Au纳米颗粒修饰的ZnO(Au-ZnO)纳米棒阵列体系。通过场发射扫描电子显微镜(FE-SEM)和X射线衍射仪(XRD)对ZnO纳米棒阵列和Au-ZnO纳米复合体系进行表面形貌表征和结构分析。气敏性能测试结果表明,Au-ZnO纳米复合体系在300℃下对1000μL·L-1甲醛的灵敏度为41.5,而在200℃下灵敏度仍能达到10.3,表明可以制备低工作温度下气敏性能良好的甲醛气敏传感器。

关 键 词:ZnO    纳米棒    甲醛    气敏性能

Preparation and Formaldehyde Gas Sensing Properties of Gold Nanoparticle Modified ZnO Nanorods Array
CHEN Wei-Liang,YIN Jing,HUANG Chun-Shu,WANG Xue-Wei,YUAN Zhi-Hao and BIE Li-Jian.Preparation and Formaldehyde Gas Sensing Properties of Gold Nanoparticle Modified ZnO Nanorods Array[J].Chinese Journal of Inorganic Chemistry,2010,26(4):586-590.
Authors:CHEN Wei-Liang  YIN Jing  HUANG Chun-Shu  WANG Xue-Wei  YUAN Zhi-Hao and BIE Li-Jian
Institution:Nanomaterials & Nanotechnology Research Center, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384,School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384,Nanomaterials & Nanotechnology Research Center, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384,Nanomaterials & Nanotechnology Research Center, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384,Nanomaterials & Nanotechnology Research Center, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384; Key Laboratory of Display Materials & Photoelectric Devices(Tianjin University of Technology) authorized by Mini and Nanomaterials & Nanotechnology Research Center, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384; Key Laboratory of Display Materials & Photoelectric Devices(Tianjin University of Technology) authorized by Mini
Abstract:zinc oxide nanorods array were synthesized directly via a two-step solution approach,and Au film was then formed on ZnO surface by vacuum evaporation,after annealing at 500℃ for 1h,Au nanoparticle modified ZnO (Au-ZnO)nanorods array was obtained.The morphology and structure of Au-ZnO nanorods array were characterized by field emission scanning electron microscope(FESEM)and X-ray diffraction(XRD).The sensitivity of Au-ZnO nanorods array to 1000μL·L~(-1) formaldehyde is 41.5 at 300℃ and 11 at 200 ℃ respectively,revealing the potential to fabricate low temperature high response formaldehyde gas sensor.
Keywords:ZnO  nanorod  formaldehyde  gas sensing property
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