| 丙二酸根-1，10-邻菲罗啉合镍(Ⅱ)配合物的合成、晶体结构及光谱性质 |
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| 引用本文： | 杨红,韩新利,张智慧,姜萍.丙二酸根-1，10-邻菲罗啉合镍(Ⅱ)配合物的合成、晶体结构及光谱性质[J].无机化学学报,2007,23(3):513-516. |
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| 作者姓名： | 杨红 韩新利 张智慧 姜萍 |
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| 作者单位： | 南开大学化学学院化学系,天津,300071 |
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| 摘 要： | A complex, NiL(Phen)2(H2O)5 (Phen=1,10 phenanthroline; L=malonate), has been synthesized and chara-cterized. Single crystal X-ray structural determination has been carried out for the complex, the crystal is triclinic system, space group P1 with a=1.042 4(4) nm, b=1.061 2(4) nm, c=1.303 8(5) nm, α=85.784(4)°, β=77.232(3)°, γ=72.879(4)°, Mr=611.24, V=1.344 2(8) nm3, Z=2. In this complex, the central metal Ni(Ⅱ) atom is in distorted octa-hedron coordination environment. The molecule is extended to 2D network by the intermolecular π-π stacking interaction. CCDC: 278766.
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| 关 键 词： | 晶体结构 镍(Ⅱ)配合物 邻菲罗啉 π-π作用 丙二酸 |
| 文章编号： | 1001-4861(2007)03-0513-04 |
| 修稿时间： | 2006-09-27 |
Synthesis, Crystal Structure and Spectrum Properties of Ni[L](Phen)2(H2O)5 (Phen=1,10-phenanthroline, L=malonate) |
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| YANG Hong,HAN Xin-Li,ZHANG Zhi-Hui and JIANG Ping.Synthesis, Crystal Structure and Spectrum Properties of Ni[L](Phen)2(H2O)5 (Phen=1,10-phenanthroline, L=malonate)[J].Chinese Journal of Inorganic Chemistry,2007,23(3):513-516. |
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| Authors: | YANG Hong HAN Xin-Li ZHANG Zhi-Hui and JIANG Ping |
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| Institution: | Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
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