| 载有C60的TiO2纳米粒子光催化活性 |
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| 引用本文： | 宋 翔,严 亚,李向清,张 静,姚平平,康诗钊,穆 劲.载有C60的TiO2纳米粒子光催化活性[J].无机化学学报,2011,27(6):1047-1052. |
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| 作者姓名： | 宋 翔 严 亚 李向清 张 静 姚平平 康诗钊 穆 劲 |
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| 作者单位： | 1. 华东理工大学化学与分子工程学院,上海,200237
2. 上海应用技术学院化工系,上海,200235 |
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| 基金项目： | 国家自然科学基金重点项目 |
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| 摘 要： | 以水溶性C60和TiO2粒子为前驱体，采用水热法制备了载有C60的锐钛矿型TiO2纳米粒子。应用X射线衍射、透射电子显微镜、红外光谱、紫外-可见漫反射光谱、荧光光谱对产物进行了表征。以对-硝基苯酚为模型污染物研究了产物的光催化活性，结果表明适量负载C60可以提高TiO2纳米粒子的光催化活性，C60起着传输电子、促进TiO2光生载流子分离的作用，且经7次循环使用后对-硝基苯酚的降解效率仍能达到74%。讨论了载有C60的TiO2纳米粒子光催化降解对-硝基苯酚的机理。
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| 关 键 词： | TiO2纳米粒子 C60 改性 光催化 |
Photocatalytic Activity of TiO2 Nanoparticles Loaded with C60 |
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| SONG Xiang,YAN Y,LI Xiang-Qing,ZHANG Jing,YAO Ping-Ping,KANG Shi-Zhao and MU Jin.Photocatalytic Activity of TiO2 Nanoparticles Loaded with C60[J].Chinese Journal of Inorganic Chemistry,2011,27(6):1047-1052. |
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| Authors: | SONG Xiang YAN Y LI Xiang-Qing ZHANG Jing YAO Ping-Ping KANG Shi-Zhao and MU Jin |
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| Institution: | School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China,School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China,Department of Chemical Engineering, Shanghai Institute of Technology, Shanghai 200235, China,School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China,School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China,Department of Chemical Engineering, Shanghai Institute of Technology, Shanghai 200235, China and School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China |
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| Abstract: | Anatase TiO2 nanoparticles loaded with C60 were prepared by a simple hydrothermal process using water-soluble C60 and TiO2 particles as precursors. The products were characterized by powder X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectra, diffuse reflectance UV-Vis and photoluminescence spectroscopy. The photocatalytic activity of the C60 loaded TiO2 catalysts was evaluated by the degradation of p-nitrophenol (PNP) under UV light irradiation. The results showed that suitable amount of C60 remarkably improved the photocatalytic activity of anatase TiO2 nanoparticles and the C60 in the catalyst played roles in transferring electrons and promoting the separation of photo-generated electron-hole pairs. In addition, PNP of 74% could be still degraded by the C60 loaded TiO2 nanoparticles after seven cycles. The photocatalytic degradation mechanism of p-nitrophenol by the C60 loaded TiO2 nanoparticles was discussed. |
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| Keywords: | TiO2 nanoparticles C60 modification photocatalysis |
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