| 基于糖苷芳香酸酯的金属有机材料的制备与研究 |
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| 引用本文： | 杨瑞环,张驰,霍冀川,曲鹏.基于糖苷芳香酸酯的金属有机材料的制备与研究[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 杨瑞环 张驰 霍冀川 曲鹏 |
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| 作者单位： | 西南科技大学材料科学与工程学院, 绵阳 621010;西南科技大学材料科学与工程学院, 绵阳 621010;新西兰奥克兰大学化学科学学院, 奥克兰 1142, 新西兰;西南科技大学材料科学与工程学院, 绵阳 621010;西南科技大学材料科学与工程学院, 绵阳 621010 |
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| 基金项目： | 四川省科技厅国际合作项目（No.2011HH0020）；西南科技大学博士基金（No.10zx7104）；西南科技大学平台科研基金（No.13zxpt08）。 |
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| 摘 要： | 选用甲基葡萄糖苷和邻苯二甲酸酐为原料，在三乙胺的催化作用下合成了具有配位能力的齿状有机酯配体甲基葡萄糖苷芳香酸酯（MGAE）（C15H18O9，C15H16O8，C22H30O14，C23H22O12，C31H26O15或C39H30O18）配体；然后，将该新型有机酯配体与金属盐溶液在模板剂三乙胺的作用下经配位制备出一系列MGAE金属有机化合物，并采用FT-IR，XRD，TGA，FSEM，EDS和BET等表征手段对所得的MGAE金属有机化合物进行表征。结果表明：配位过程中主要是MGAE中的羰基参与反应，且影响配合物性能的主要是MGAE中的有机配体和金属阳离子。
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| 关 键 词： | 甲基葡萄糖苷 MGAE MGAE-金属配合物 金属有机材料 |
Preparation and Study of a Novel Glucoside Aromatic Ester Based Metal Organic Material |
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| YANG Rui-Huan,ZHANG Chi,HUO Ji-Chuan and QU Peng.Preparation and Study of a Novel Glucoside Aromatic Ester Based Metal Organic Material[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | YANG Rui-Huan ZHANG Chi HUO Ji-Chuan and QU Peng |
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| Institution: | School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;School of Chemical Sciences, The University of Auckland, Auckland 1142, New Zealand;School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China |
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| Abstract: | Dentate organic ester ligandsmethyl glucoside aromatic ester based ligands (MGAE ligand) (C15H18O9, C15H16O8, C22H30O14, C23H22O12, C31H26O15 or C39H30O18) with complexation ability were, through the catalysis of triethylamine, synthesized using methyl glucoside and phthalic anhydride as selected raw materials. Then, a series of MGAEligand based metal-organic coordination compounds were prepared in the involvement of triethylamine as a template agent through complexing the new type of organic ligands with metal salt solution,Then the MGAE ligand based complexes were characterized using FT-IR, XRD, TGA, FSEM, EDS and BET. The results showed that the complexation is chiefly due to the involvement of carbonyl in the MGAE ligand and the performance of complexes is mainly influenced by the MGAE ligands and metal cations. |
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| Keywords: | methy glucoside MGAE MGAE-metal complex metal organic material |
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