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低热固相合成化学
引用本文:周益明,忻新泉.低热固相合成化学[J].无机化学学报,1999,15(3):273-292.
作者姓名:周益明  忻新泉
作者单位:南京大学配位化学研究所,配位化学国家重点实验室,南京,210093
基金项目:国家自然科学基金,教育部博士点基金
摘    要:本文介绍了固相化学反应,概述了高热、中热、低热固相反应在合成化学中的地位,重点阐述了低热固相反应的特征及其在无机、有机、材料化学中的应用,列举已在工业生产中使用的低热固相反应实例,阐明低热固相合成确实是工业生产中一条节能、高效、减污的理想通道。

关 键 词:低热固相反应  合成化学  纳米材料  非线性光学材料  工业应用

SYNTHETIC CHEMISTRY FOR SOLID STATE REACTION AT LOW-HEATING TEMPERATURES
ZHOU Yi-Ming and XIN Xin-Quan.SYNTHETIC CHEMISTRY FOR SOLID STATE REACTION AT LOW-HEATING TEMPERATURES[J].Chinese Journal of Inorganic Chemistry,1999,15(3):273-292.
Authors:ZHOU Yi-Ming and XIN Xin-Quan
Institution:Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093
Abstract:A reasonable definition for a solid state reaction is presented. And the position in synthetic chemistry for a solid state reaction at high, moderate, low-heating temperatures is described, respectively. The characteristics and the potential applications of a solid state reaction at low-heating temperatures to synthetic chemistry, especially in the syntheses of nanocrystals and non-linear optical materials, are emphasized. Some typical examples in chemical industry are illustrated to show that the application of the solid state reaction at low-heating temperatures should be developed in the future chemical industry due to its advantages of conserving energy, achieving good yield, being absent of solvent, and producing almost no pollution.
Keywords:low-heating temperature  solid state reaction  synthetic chemistry  nanocrystal    non-linear optical materials  industrial application
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