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钙钛矿ABX3型材料的结构与性质调控
引用本文:陆新荣,赵颖,刘建,李承辉,游效曾.钙钛矿ABX3型材料的结构与性质调控[J].无机化学学报,2013,29(18).
作者姓名:陆新荣  赵颖  刘建  李承辉  游效曾
作者单位:南京大学化学化工学院, 配位化学国家重点实验室, 南京微结构国家实验室, 人工微结构科学与技术协同创新中心, 南京 210093,南京大学化学化工学院, 配位化学国家重点实验室, 南京微结构国家实验室, 人工微结构科学与技术协同创新中心, 南京 210093,南京大学化学化工学院, 配位化学国家重点实验室, 南京微结构国家实验室, 人工微结构科学与技术协同创新中心, 南京 210093,南京大学化学化工学院, 配位化学国家重点实验室, 南京微结构国家实验室, 人工微结构科学与技术协同创新中心, 南京 210093,南京大学化学化工学院, 配位化学国家重点实验室, 南京微结构国家实验室, 人工微结构科学与技术协同创新中心, 南京 210093
基金项目:国家重点基础研究发展规划项目(No.2011CB933300)、国家教育部博士点专项基金(No.20120091130002)、江苏省科技支撑计划项目资助(No.BE2014147-2)等资助项目。
摘    要:近年来,钙钛矿太阳能电池由于其效率高、制造成本低、工艺简单等特点受到广泛关注,成为目前太阳能电池领域的研究热点。在钙钛矿太阳能电池中,无机-有机杂化ABX3材料非常重要。它既作为光吸收材料,同时又作为载流子传输材料,因此它的光电性质直接影响到太阳能电池的效率。本文综述了调控钙钛矿型无机有机金属卤化物ABX3结构和性质的几种途径。

关 键 词:钙钛矿  太阳能电池  光谱  晶体结构  调控
收稿时间:2015/5/20 0:00:00
修稿时间:2015/7/20 0:00:00

Modulation of the Structure and Property of Perovskite Type ABX3 Material
LU Xin-Rong,ZHAO Ying,LIU Jian,LI Cheng-Hui and YOU Xiao-Zeng.Modulation of the Structure and Property of Perovskite Type ABX3 Material[J].Chinese Journal of Inorganic Chemistry,2013,29(18).
Authors:LU Xin-Rong  ZHAO Ying  LIU Jian  LI Cheng-Hui and YOU Xiao-Zeng
Institution:State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China,State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China,State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China,State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China and State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
Abstract:Perovskite solar cells have been receiving intensive attentions and become a hot research topic in solar cells, due to their high photo-to-electric conversion efficiency, low manufacturing cost and simple fabrication process. In perovskite solar cell, the perovskite type inorganic-organic hybrid ABX3 material functions as light absorbing layer as well as charge carrier transporting material. Therefore, the properties of ABX3 will directly affect the performance of perovskite solar cell. In this paper, we review on the present methods to tune the structure and properties of perovskite type inorganic-organic hybrid ABX3 material.
Keywords:perovskite  solar cell  spectrum  crystal structure  modulation
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