| 一维链状配位聚合物{[Cd2(1，8-nap)2(H2O)2](bpp)2}n的水热合成、晶体结构及荧光性质 |
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| 引用本文： | 封 霞,唐治炜,冯云龙,蓝尤钊,温一航.一维链状配位聚合物{[Cd2(1，8-nap)2(H2O)2](bpp)2}n的水热合成、晶体结构及荧光性质[J].无机化学学报,2008,24(10):1713-1717. |
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| 作者姓名： | 封 霞 唐治炜 冯云龙 蓝尤钊 温一航 |
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| 作者单位： | 浙江师范大学物理化学研究所,浙江省固体表面反应化学重点实验室,金华,321004 |
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| 基金项目： | 浙江省同体表面反应化学重点实验室开放基金 |
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| 摘 要： | The title complex, {Cd2(1，8-nap)2(H2O)2](bpp)2}n(1), a cadmium complex based on mixed naphthalene-1,8-dicarboxylate (1,8-nap) and flexible 1,3-bi(4-pyridyl)propane (bpp) ligands, has been hydrothermally synthes-ized. It consists of a one-dimensional chain along c axis, which is derived from dimeric unit Cd2(1,8-nap)2(H2O)2] linked by a pair of bpp ligands. In every Cd2(1,8-nap)2(H2O)2] dimeric unit, two 1,8-nap act as bridging ligands to connect two Cd(Ⅱ) atoms, forming a sixteen-membered ring. Each Cd(Ⅱ) atom is in a distorted octahedral environment, coordinated by one aqua, two 1,8-nap and two bridging bpp ligands. In addition, two bridging bpp ligands connected two neighboring Cd(Ⅱ) atoms form a twenty-four-membered ring. The TGA and Luminescence property in solid state of complex 1 have been further studied and discussed in this paper. CCDC: 669293.
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| 关 键 词： | 镉(Ⅱ)配合物 晶体结构 荧光性质 cadmium(Ⅱ) complex |
Hydrothermai Synthesis, Crystal Structure and Luminescence Property of a 1D Chain Coordination Polymer {[Cd2(1,8-nap)2(H2O)2](bpp)2}n |
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| FENG Xi,TANG Zhi-Wei,FENG Yun-Long,LAN You-Zhao and WEN Yi-Hang.Hydrothermai Synthesis, Crystal Structure and Luminescence Property of a 1D Chain Coordination Polymer {[Cd2(1,8-nap)2(H2O)2](bpp)2}n[J].Chinese Journal of Inorganic Chemistry,2008,24(10):1713-1717. |
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| Authors: | FENG Xi TANG Zhi-Wei FENG Yun-Long LAN You-Zhao and WEN Yi-Hang |
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| Institution: | Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004 and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004 |
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| Abstract: | The title complex, {Cd2(1,8-nap)2(H2Oh](bpp)2}n (1), a cadmium complex based on mixed naphthalene-1,8-dicarboxylate (1,8-nap) and flexible 1,3-bi (4-pyridyl)propane (bpp) ligands, has been hydrothermally synthes-ized. It consists of a one-dimensional chain along c axis, which is derived from dimeric unit Cd2(1,8-nap)2(H2O)2]linked by a pair of bpp ligands. In every {Cd2(1,8-nap)2(H2O)2]dimeric unit, two 1,8-nap act as bridging ligands toconnect two Cd (Ⅱ) atoms, forming a sixteen-membered ring. Each Cd (Ⅱ) atom is in a distorted octahedralenvironment, coordinated by one aqua, two 1,8-nap and two bridging bpp ligands. In addition, two bridging bppligands connected two neighboring Cd (Ⅱ) atoms form a twenty-four-membered ring. The TGA and Luminescenceproperty in solid state of complex 1 have been further studied and discussed in this paper. |
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| Keywords: | crystal structure luminescence property |
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