| 基于硼二吡咯亚甲基类(BODIPY)衍生物的合成,光谱及汞离子识别(英文) |
| |
| 引用本文： | 姜佳丽,卢 华,沈 珍.基于硼二吡咯亚甲基类(BODIPY)衍生物的合成,光谱及汞离子识别(英文)[J].无机化学学报,2010,26(6):1105-1108. |
| |
| 作者姓名： | 姜佳丽 卢 华 沈 珍 |
| |
| 作者单位： | 南京大学化学化工学院,配位化学国家重点实验室,南京210093 |
| |
| 基金项目： | 国家自然科学基金面上基金项目，教育部新世纪优秀人才支持计划 |
| |
| 摘 要： | The synthesis and sensing properties of a new BODIPY derivative 1 are outlined. 1 shows fluorescence “turn-on” and colorimetric responses with high selectivity toward Hg2+ over the other metal cations. Coordination of Hg2+ influences the electronic properties of the receptor at meso-position and alter the efficiency of non-radiative decay, hence increase the fluorescence intensity and red shift the absorption spectrum.
|
| 关 键 词： | 汞离子 硼二吡咯亚甲基 荧光探针 |
Synthesis, Spectroscopic Properties and Hg2+ Recognition Based on a Boron Dipyrromethene Dye (BODIPY) |
| |
| JIANG Jia-Li,LU Hua and SHEN Zhen.Synthesis, Spectroscopic Properties and Hg2+ Recognition Based on a Boron Dipyrromethene Dye (BODIPY)[J].Chinese Journal of Inorganic Chemistry,2010,26(6):1105-1108. |
| |
| Authors: | JIANG Jia-Li LU Hua and SHEN Zhen |
| |
| Institution: | School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
| |
| Abstract: | The synthesis and sensing properties of a new BODIPY derivative 1 are outlined. 1 shows fluorescence "turn-on" and colorimetric responses with high selectivity toward Hg2+ over the other metal cations. Coordination of Hg2+ influences the electronic properties of the receptor at meso-position and alter the efficiency of non-radiative decay, hence increase the fluorescence intensity and red shift the absorption spectrum. |
| |
| Keywords: | Hg2+ boron-dipyrromethene fluorescent sensor |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
