| 新型三维间排层状钴磷酸盐配合物Co3(PO4)2·6H2O的合成与晶体结构 |
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| 引用本文： | 乔海滨,申小清,张鸿云,毛红艳,杜晨霞,吴庆安,刘玉坤,侯红卫.新型三维间排层状钴磷酸盐配合物Co3(PO4)2·6H2O的合成与晶体结构[J].无机化学学报,2005,21(8):1191-1194. |
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| 作者姓名： | 乔海滨 申小清 张鸿云 毛红艳 杜晨霞 吴庆安 刘玉坤 侯红卫 |
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| 作者单位： | 郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学材料科学与工程学院，郑州 450052,郑州大学化学系，郑州 450052 |
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| 基金项目： | 国家自然科学基金资助项目(No.20271046),河南省教育厅自然科学基金项目(No.2004150004). |
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| 摘 要： | A new three dimensional layered cobalt phosphate complex Co3(PO4)2·6H2O, was prepared by hydro-thermal reaction of Co(CH3COO)2·4H2O and H3PO4, NH4VO3. The crystal structure of the complex was deter-mined by single-crystal X-ray diffraction. The result indicates that it crystallizes in the tetragonal space group I4/m. It rarely occurs in cobalt phosphate complex to form two kinds of coordinate geometry of Co(Ⅱ), six water molecular oxygen atoms surround Co(Ⅰ) and form an octahedron geometry, Co(2) bond to four oxygen atoms from 4PO43- and one water molecular oxygen and build a tetragonal pyramid. The kinetic study shows that the first decomposition stage is governed by A(?)B(?)C mode. CSD: 414600.
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| 关 键 词： | 磷酸盐 水热合成 配位化合物 |
| 文章编号： | 1001-4861(2005)08-1191-04 |
| 收稿时间： | 2004/11/23 0:00:00 |
| 修稿时间： | 2004年11月23 |
Synthesis and Crystal Structure of a Novel Three Dimensional Layered Cobalt Phosphate Complex Co3(PO4)2· 6H2O |
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| QIAO Hai-Bin,SHEN Xiao-Qing,ZHANG Hong-Yun,MAO Hong-Yan,DU Chen-Xi,WU Qing-An,LIU Yu-Kun and HOU Hong-Wei.Synthesis and Crystal Structure of a Novel Three Dimensional Layered Cobalt Phosphate Complex Co3(PO4)2· 6H2O[J].Chinese Journal of Inorganic Chemistry,2005,21(8):1191-1194. |
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| Authors: | QIAO Hai-Bin SHEN Xiao-Qing ZHANG Hong-Yun MAO Hong-Yan DU Chen-Xi WU Qing-An LIU Yu-Kun and HOU Hong-Wei |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,School of Materials Science and Engnieering, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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| Abstract: | |
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| Keywords: | phosphate hydro-thermal synthesis coordination polymer kinetics |
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