| 亚微米级Ag2S空心球的乳液法合成 |
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| 引用本文： | 司 玲,王利侠,张 杰,包建春,李 邨,梁永晔,徐 正.亚微米级Ag2S空心球的乳液法合成[J].无机化学学报,2003,19(11):1253-1256. |
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| 作者姓名： | 司 玲 王利侠 张 杰 包建春 李 邨 梁永晔 徐 正 |
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| 作者单位： | 1. 南京师范大学化学与环境科学学院,材料科学实验室,南京,210097
2. 南京大学配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家自然科学基金资助项目(No.20073021)，江苏省教育厅自然科学基金资助项目(No.01KJB150005)，南京市政府自然科学基金资助项目。 |
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| 摘 要： | Hollow Ag2S spheres have been prepared via hydrolyze reaction of Ag2S2O3， which formed from the reaction of AgNO3 with Na2S2O3， in cyclohexane/water/polyglycol emulsion system. It was found that the component of the reaction system has a significant influence on the formation of hollow Ag2S spheres. The possible formation mech-anism of the hollow Ag2S spheres in the emusion system was also discussed.
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| 关 键 词： | Ag2S 空心球 聚乙二醇 乳浊液 |
| 修稿时间： | 2003年6月18日 |
Synthesis of Hollow Ag2S Submicrometer Spheres by Emulsion Method |
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| SI Ling,WANG Li-Xi,ZHANG Jie,BAO Jian-Chun,LI Cun,LIANG Yong-Ye and Xu Zheng.Synthesis of Hollow Ag2S Submicrometer Spheres by Emulsion Method[J].Chinese Journal of Inorganic Chemistry,2003,19(11):1253-1256. |
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| Authors: | SI Ling WANG Li-Xi ZHANG Jie BAO Jian-Chun LI Cun LIANG Yong-Ye and Xu Zheng |
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| Abstract: | Hollow Ag2S spheres have been prepared via hydrolyze reaction of Ag2S2O3, which formed from the reaction of AgNO3 with Na2S2O3, in cyclohexane/water/polyglycol emulsion system. It was found that the component of the reaction system has a significant influence on the formation of hollow Ag2S spheres. The possible formation mechanism of the hollow Ag2S spheres in the emusion system was also discussed. |
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| Keywords: | Ag2S hollow sphere emulsion polyethylene glycol |
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