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二氧化钛多孔纳米片在染料敏化太阳电池中的应用
引用本文:胡嘉清,雷炳新,孙振范,孙伟,张宪玺.二氧化钛多孔纳米片在染料敏化太阳电池中的应用[J].无机化学学报,2013,29(18).
作者姓名:胡嘉清  雷炳新  孙振范  孙伟  张宪玺
作者单位:海南师范大学化学与化工学院, 海口 571158;海南师范大学化学与化工学院, 海口 571158;海南师范大学化学与化工学院, 海口 571158;海南师范大学化学与化工学院, 海口 571158;聊城大学化学化工学院 山东省化学储能与新型电池技术重点实验室, 聊城 252000
基金项目:资国家自然科学基金(No.2011CBA00701),国家重点基础研究发展计划(No.21171084)和海南省自然科学基金(No.212013和213015)资助项目。
摘    要:运用连续吸附反应法和化学腐蚀-沉积法,用ZnO/FTO(氟掺杂氧化锡)多孔纳米片为模板,制备了TiO2/FTO多孔纳米片。研究了吸附次数对形貌、光散射性能和染料敏化太阳电池性能的影响。最佳吸附次数为30,由此得到的太阳能电池的效率、短路电流密度Jsc、开路电压Voc和填充因子FF分别为:5.57%、9.26mA·cm-2、0.835V和72.04%。这个效率略高于P25(5.32%),但远高于ZnO(2.41%)。

关 键 词:纳米片  多孔电极  二氧化钛  染料敏化太阳电池
修稿时间:5/5/2014 12:00:00 AM

Porous TiO2 Nanosheets Films for Dye-Sensitized Solar Cells
HU Jia-Qing,LEI Bing-Xin,SUN Zhen-Fan,SUN Wei and ZHANG Xian-Xi.Porous TiO2 Nanosheets Films for Dye-Sensitized Solar Cells[J].Chinese Journal of Inorganic Chemistry,2013,29(18).
Authors:HU Jia-Qing  LEI Bing-Xin  SUN Zhen-Fan  SUN Wei and ZHANG Xian-Xi
Institution:School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China;School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China;School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China;School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China;Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China
Abstract:Astrategy was presented for synthesizing TiO2 nanosheets on fluorine-doped tin oxide (FTO) glass substrate through layer-by-layer absorption and reaction (LBL-AR) method using porous ZnO nanosheets as a template, followed by wet-chemical etching and depositing process. The effect of immersing cycles on the morphology, optical property and performance of dye-sensitized solar cells (DSSCs) has been demonstrated. Amaximum efficiency of 5.57% is obtained from 30 cycles of immersing, with a short-circuit current density (Jsc) of 9.26 mA·cm-2, open-circuit voltage (Voc) of 0.835 V and fill factor (FF) of 72.04%. The maximum efficiency achieved is a little higher than that of cell-P25 (5.32%) and much higher than that of ZnO nanosheets (2.41%).
Keywords:nanosheet  porous electrode  TiO2  dye-sensitized solar cell
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