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微孔化合物生成中的结构导向与模板作用
引用本文:李激扬,于吉红,徐如人.微孔化合物生成中的结构导向与模板作用[J].无机化学学报,2004,20(1):1-16.
作者姓名:李激扬  于吉红  徐如人
作者单位:吉林大学无机合成与制备化学国家重点实验室,化学学院,长春,130023
基金项目:国家重点 基础研究资助项目(No.G2000077507)
摘    要:本文详细总结了各种客体分子或离子在无机微孔化合物生成中的结构导向与模板作用。讨论了不同合成体系中,客体与无机骨架间的非键相互作用对生成骨架结构的影响以及分子模拟在研究主-客体关系、结构导向剂设计与筛选等方面的进展。无机或有机客体与无机骨架间关系规律的研究,有助于进一步理解结构导向剂(3DA)作用的机理和微孔化合物的晶化与生成机制,对特定结构微孔化合物的定向合成具有一定的意义。

关 键 词:无机微孔化合物  结构导向剂  主-客体作用  分子模拟

The Structure Directing and Templating Effects in the Formation of Microporous Compounds
LI Ji-Yang,YU Ji-Hong and XU Ru-Ren.The Structure Directing and Templating Effects in the Formation of Microporous Compounds[J].Chinese Journal of Inorganic Chemistry,2004,20(1):1-16.
Authors:LI Ji-Yang  YU Ji-Hong and XU Ru-Ren
Institution:State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Col lege of Chemistry, Jilin University, Changchun130023,State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Col lege of Chemistry, Jilin University, Changchun130023 and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Col lege of Chemistry, Jilin University, Changchun130023
Abstract:The structure direct ing effects of various guest molecules or ions in the formation of inorganic mic roporous compounds are reviewed.The non-bond interactions of the guest-host i n different systems are investigated,which usually determine the structures of inorganic frameworks.We also outline the recent advances of molecular simulatio ns on the study of the interactions of host-guest,as well as the design and se lection of organic molecules in directing the rational synthesis.The study of t he relations between the guest molecules and host frameworks will assist in furt her understanding the structure directing role of the guest molecules and the cr ystallization mechanism in the formation of microporus compounds.
Keywords:inor ganic microporous compounds structure directing agent interaction of host-guest  molecular simulation  
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