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ZnO纳米棒阵列的同步法制备及其PL性能研究
引用本文:王百齐,王鹏伟,张学进,章新政,付宏刚,井立强,俞大鹏.ZnO纳米棒阵列的同步法制备及其PL性能研究[J].无机化学学报,2007,23(8):1365-1368.
作者姓名:王百齐  王鹏伟  张学进  章新政  付宏刚  井立强  俞大鹏
作者单位:1. 介观物理国家重点实验室电子显微实验室,北京大学物理学院,北京,100871
2. 黑龙江大学化学化工与材料学院,物理化学实验室,哈尔滨,150080
基金项目:国家自然科学基金;国家重点基础研究发展计划(973计划);黑龙江省自然科学基金;黑龙江省教育厅骨干教师基金
摘    要:在较低温度下,采用化学法在Zn片和玻璃片上同步制备了ZnO纳米棒阵列。利用XRD、FESEM和HRTEM对样品进行了表征,并且通过光致发光谱研究了阵列的光致发光(PL)性能。结果表明,ZnO纳米棒阵列较为致密、取向性较好。纳米棒为六方纤锌矿相,沿c轴生长,平均直径约为60 nm。同步法制备的2种ZnO纳米棒阵列均具有较好的紫外和橙红色发光性能,但发光特性却存在一定差异,这可能主要是由于2种阵列中纳米棒的缺陷含量不同所致。

关 键 词:ZnO    纳米棒阵列    同步法制备    光致发光性能
文章编号:1001-4861(2007)08-1365-04
修稿时间:2006-03-122007-03-19

ZnO Nanorod Arrays: Synchronous Preparation and PL Performances
WANG Bai-Qi,WANG Peng-Wei,ZHANG Xue-Jin,ZHANG Xin-Zheng,FU Hong-Gang,JING Li-Qiang and YU Da-Peng.ZnO Nanorod Arrays: Synchronous Preparation and PL Performances[J].Chinese Journal of Inorganic Chemistry,2007,23(8):1365-1368.
Authors:WANG Bai-Qi  WANG Peng-Wei  ZHANG Xue-Jin  ZHANG Xin-Zheng  FU Hong-Gang  JING Li-Qiang and YU Da-Peng
Institution:1Electron Microscopy Laboratory,State Key Laboratory for Mesoscopic Physics,School of Physics,Peking University,Beijing 100871;2Laboratory of Physical Chemistry,School of Chemistry and Material Sciences,Heilongjiang University,Harbin 150080
Abstract:ZnO nanorod arrays were synchronously prepared on Zn piece and substrate by means of chemical method under low temperature. The ZnO arrays were characterized using XRD,SEM and HRTEM,and the photoluminescence performances of the arrays were principally investigated. The results show that ZnO nanorod arrays are dense and exhibit good orientation. The individual ZnO nanorod grows along with c-axis with size about 60 nm,and the nanorod is with Wurtzite structure. In addition,the ZnO nanorod arrays both on Zn piece and on substrate emit strong ultraviolet,while there are different performances in salmon pink emission,which results possibly from different defect contents in nanorods of two arrays on Zn piece and substrate.
Keywords:ZnO  nanorod arrays  synchronous preparation  photoluminescence performance
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