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新型含葡萄糖基手性Salen配体及其Mn3+、Fe3+、Co2+、Cu3+配合物的合成与表征
引用本文:赵姗姗,赵继全,赵东敏.新型含葡萄糖基手性Salen配体及其Mn3+、Fe3+、Co2+、Cu3+配合物的合成与表征[J].无机化学学报,2006,22(6):1133-1136.
作者姓名:赵姗姗  赵继全  赵东敏
作者单位:河北工业大学化工学院,天津,300130
摘    要:A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde)]-α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.

关 键 词:葡萄糖衍生物    手性金属配合物    Salen配体    Schiff碱    环己二胺
文章编号:1001-4861(2006)06-1133-04
收稿时间:2006-02-20
修稿时间:2006-05-08

Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes
ZHAO Shan-Shan,ZHAO Ji-Quan and ZHAO Dong-Min.Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes[J].Chinese Journal of Inorganic Chemistry,2006,22(6):1133-1136.
Authors:ZHAO Shan-Shan  ZHAO Ji-Quan and ZHAO Dong-Min
Institution:School of Chemical Engineering, Hebei University of Technology, Tianjin 300130,School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 and School of Chemical Engineering, Hebei University of Technology, Tianjin 300130
Abstract:
Keywords:glucose derivative  chiral metal complex  Salen ligand  Schiff base  diaminocyclohexane
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