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复合粒子涂膜表面疏水性能分形评价
引用本文:曲爱兰,程 江,杨卓如.复合粒子涂膜表面疏水性能分形评价[J].无机化学学报,2010,26(4):615-620.
作者姓名:曲爱兰  程 江  杨卓如
作者单位:1. 暨南大学生命科学学院化学系,广州,510632
2. 华南理工大学化工学院,广州,510640
摘    要:采用接枝法和非均相乳液聚合与溶胶-凝胶法相结合技术,制备了不同形状的复合粒子,经低表面能的物质修饰后,其涂膜表面具有超疏水性。采用分形理论对涂膜表面疏水性进行评价,用分形维数表征涂膜表面微观形貌与疏水性能之间的关系,结果表明对于粗糙结构表面,分形维数较粗糙度因子能更好地反映表面形貌对水接触角的影响。

关 键 词:分形理论    复合粒子    疏水性

Hydrophobicity on Film Surfaces with Composite Particles Estimated by Fractal Theory
QU Ai-Lan,CHENG Jiang and YANG Zhuo-Ru.Hydrophobicity on Film Surfaces with Composite Particles Estimated by Fractal Theory[J].Chinese Journal of Inorganic Chemistry,2010,26(4):615-620.
Authors:QU Ai-Lan  CHENG Jiang and YANG Zhuo-Ru
Institution:Deaprtment of Chemistry, College of Life and Science Technology, Jinan University, Guangzhou 510632,The School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640 and The School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640
Abstract:Composite particles were prepared by grafting method and emulsion polymerization combined with sol-gel method. Hydrophobicity was shown on the film surface with composite particles after modification by material with low surface energy. Fractal theory was used to estimate the hydrophobicity and the relation between the surface morphologies and hydrophobicity was characterized by fractal dimension. The results show that fractal dimension can be more appropriate than roughness factor for characterization the morphology effect on hydrophobicity.
Keywords:fractal theory  composite particles  hydrophobicity
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