| 一维链状超分子化合物[Zn(dafo)2(H2O)2](NO3)2(dafo=4，5-二氮芴-9-酮)的合成、表征和晶体结构 |
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| 引用本文： | 徐 晨,毛红艳,张鸿云,刘红磊,吴庆安,侯红卫,朱 玉.一维链状超分子化合物[Zn(dafo)2(H2O)2](NO3)2(dafo=4，5-二氮芴-9-酮)的合成、表征和晶体结构[J].无机化学学报,2004,20(5):539-542. |
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| 作者姓名： | 徐 晨 毛红艳 张鸿云 刘红磊 吴庆安 侯红卫 朱 玉 |
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| 作者单位： | 郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052 |
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| 基金项目： | 国家自然科学基金资助(No.20271046)，河南省自然科学基金资助(No.0211020300)，河南省教育厅自然科学基金(No.20011500027)。 |
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| 摘 要： | A novel one-dimensional chain complex Zn(dafo)2(H2O)2](NO3)2 was synthesized. It has been characterized by IR, UV, TGA, Elemental analysis and X-ray diffraction analysis. The crystal belongs to triclinic system, P1 space group. The Crystallographic data are: a= 0.702 7(14) nm, b= 0.828 95(17) nm, c= 10.225(2) nm, α = 95.02(3)°, β = 91.45(3)°, γ = 99.85(3)°. The crystal structure data indicate that the Zn(Ⅱ) ion was coordinated with the four nitrogen atoms of two dafo and two oxygen atoms of two coordination water molecules, respectively. The complex has a one-dimensional chain structure, which is formed by hydrogen bonds.
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| 关 键 词： | 4，5-二氮芴-9-酮 超分子化合物 Zn(Ⅱ)配合物 晶体结构 |
| 修稿时间： | 2003年7月2日 |
Preparation, Characterization and Crystal Structure and of a One-dimensional Chain Supramolecular Compound [Zn(dafo)2(H2O)2](NO3)2 (dafo=4,5-Diazafluorene-9-one) |
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| XU Chen,MAO Hong-Yan,ZHANG Hong-Yun,LIU Hong-Lei,WU Qing-An,HOU Hong-Wei and ZHU Yu.Preparation, Characterization and Crystal Structure and of a One-dimensional Chain Supramolecular Compound [Zn(dafo)2(H2O)2](NO3)2 (dafo=4,5-Diazafluorene-9-one)[J].Chinese Journal of Inorganic Chemistry,2004,20(5):539-542. |
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| Authors: | XU Chen MAO Hong-Yan ZHANG Hong-Yun LIU Hong-Lei WU Qing-An HOU Hong-Wei and ZHU Yu |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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