| 配合物Cu(C15H12N2O3)(C5H5N)的合成和晶体结构 |
| |
| 引用本文： | 陈小华,刘世雄.配合物Cu(C15H12N2O3)(C5H5N)的合成和晶体结构[J].无机化学学报,2004,20(6):668-670. |
| |
| 作者姓名： | 陈小华 刘世雄 |
| |
| 作者单位： | 福州大学中心实验室,福州,350002 |
| |
| 基金项目： | 福建省自然科学基金资助项目(No.E0110010) |
| |
| 摘 要： | The title coordination compound with N-substituted-salicyl Schiff ligand, Cu(C15H12N2O3)(C5H5N), has been synthesized. The coordination compound crystallizes in orthorhombic system, space group Pbca with a=2.037 62(7) nm, b=0.698 45(2)nm, c=2.508 76(9)nm, V=3.570 4(2) nm3, Z=8, F(000)=1 688, Dc=1.529 g·cm-3, Mr=410.91, μ=1.250 mm-1, R=0.031 3 and wR=0.077 0. In the coordination compound, one phenolate oxygen, one carbonyl oxygen and one hydrazine nitrogen atom from the dianionic ligand N-salicylaldehyde-N′-(4-methoxybenzoyl) hydrazone and one pyridine nitrogen atom coordinate to Cu(Ⅱ) ion, forming a distorted square plane. CCDC: 218182.
|
| 关 键 词： | 铜配合物 酰腙 N-取代水杨基Schiff碱 晶体结构 |
| 修稿时间： | 2003年10月10 |
Synthesis and Crystal Structure of Complex Cu(C15H12N2O3)(C5H5N) |
| |
| CHEN Xiao-Hua and LIU Shi-Xiong.Synthesis and Crystal Structure of Complex Cu(C15H12N2O3)(C5H5N)[J].Chinese Journal of Inorganic Chemistry,2004,20(6):668-670. |
| |
| Authors: | CHEN Xiao-Hua and LIU Shi-Xiong |
| |
| Institution: | Central Laboratory, Fuzhou University, Fuzhou 350002 and Central Laboratory, Fuzhou University, Fuzhou 350002 |
| |
| Abstract: | |
| |
| Keywords: | copper complex hydrazone N-substituted-salicyl Schiff ligand crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
