| 基于二乙醇胺配体的[Dy2Co8]型配合物的合成、晶体结构和磁性分析 |
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| 引用本文： | 郁有祝,郭玉华,申艳红,杨立国,牛永生,郑晓明,张海辉,王芳.基于二乙醇胺配体的[Dy2Co8]型配合物的合成、晶体结构和磁性分析[J].无机化学学报,2018,34(5):967-972. |
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| 作者姓名： | 郁有祝 郭玉华 申艳红 杨立国 牛永生 郑晓明 张海辉 王芳 |
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| 作者单位： | 安阳工学院化学与环境工程学院 |
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| 基金项目： | 国家自然科学基金（No.21302003）、河南省科技攻关项目（No.182102210200）和安阳工学院校基金项目（No.YJJ2015008）资助。 |
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| 摘 要： | 以二乙醇胺为配体合成了一种具有Dy_2Co_8]核结构的配合物Dy_2Co_8(L)_4(HL)_4(HCOO)_4(OH)_2Cl_2(CH_3OH)_2]Cl_2·4CH_3OH·2H_2O(1)(H_2L=二乙醇胺),并对其进行了X射线单晶衍射、红外光谱、元素分析和磁性表征。该配合物属于三斜晶系,P1空间群。晶体学数据:a=1.160 4(8)nm,b=1.322 7(9)nm,c=1.465 3(9)nm,α=71.181(7)°,β=67.638(7)°,γ=65.939(7)°。在晶体结构中,每一个Dy(Ⅲ)都是九配位,而每一个Co(Ⅱ)均为六配位。
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| 关 键 词： | 二乙醇胺 晶体结构 镝-钴配合物 磁性 |
| 收稿时间： | 2017/10/24 0:00:00 |
| 修稿时间： | 2018/1/30 0:00:00 |
Synthesis, Crystal Structure and Magnetism of a[Dy2Co8] Core Complex with Diethanolamine Ligand |
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| YU You-Zhu,GUO Yu-Hu,SHEN Yan-Hong,YANG Li-Guo,NIU Yong-Sheng,ZHENG Xiao-Ming,ZHANG Hai-Hui and WANG Fang.Synthesis, Crystal Structure and Magnetism of a[Dy2Co8] Core Complex with Diethanolamine Ligand[J].Chinese Journal of Inorganic Chemistry,2018,34(5):967-972. |
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| Authors: | YU You-Zhu GUO Yu-Hu SHEN Yan-Hong YANG Li-Guo NIU Yong-Sheng ZHENG Xiao-Ming ZHANG Hai-Hui and WANG Fang |
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| Institution: | College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China,College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China,College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China,College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China,College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China,College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China,College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China and College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China |
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| Abstract: | |
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| Keywords: | diethanolamine crystal structure dysprosium-cobalt complex magnetic properties |
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