| 过渡金属氢化物和聚集双键化合物反应的研究——Ⅴ.Cp2MH2(M=Zr,Hf)与RNCS(R=n-Bu,c-C6H11,C6H5,2-C10H7)、CS2的反应 |
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| 引用本文： | 王梅,陆世维,贝浼智,郭和夫.过渡金属氢化物和聚集双键化合物反应的研究——Ⅴ.Cp2MH2(M=Zr,Hf)与RNCS(R=n-Bu,c-C6H11,C6H5,2-C10H7)、CS2的反应[J].无机化学学报,1993,9(3):275-278. |
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| 作者姓名： | 王梅 陆世维 贝浼智 郭和夫 |
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| 作者单位： | 中国科学院大连化学物理研究所, 大连 116023,中国科学院大连化学物理研究所, 大连 116023,中国科学院大连化学物理研究所, 大连 116023,中国科学院大连化学物理研究所, 大连 116023 |
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| 基金项目： | 中国科学院科学基金资助的课题 |
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| 摘 要： | 本文研究了Cp2ZrH2与CS2、RNCS(R=n-Bu,c-C6H11,C6H5,2-C10H7)和Cp2HfH2与c-C6H11NCS的反应,探讨了在这类新型脱硫反应中锆氢与铪氢配合物化学反应性能上的差异.从以上反应中分
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| 关 键 词： | 过渡金属 氢化物 脱硫反应 |
| 收稿时间： | 4/4/1992 12:00:00 AM |
STUDIES ON REACTIONS OF TRANSITION-METAL HYDRIDES WITH HETEROCUMULENES V.REACTIONS OF Cp2MH2 (M=Zr, Hf) WITH RNCS (R=n-Bu, c-C6H11, C6H5, 2-C10H7), CS2 |
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| Wang Mei,Lu Shiwei,Bei Meizhi and Guo Hefu.STUDIES ON REACTIONS OF TRANSITION-METAL HYDRIDES WITH HETEROCUMULENES V.REACTIONS OF Cp2MH2 (M=Zr, Hf) WITH RNCS (R=n-Bu, c-C6H11, C6H5, 2-C10H7), CS2[J].Chinese Journal of Inorganic Chemistry,1993,9(3):275-278. |
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| Authors: | Wang Mei Lu Shiwei Bei Meizhi and Guo Hefu |
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| Institution: | Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023,Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023,Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023 and Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023 |
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| Abstract: | A new type of desulfurization reaction was investigated in our laboratory.Two sulfur-bridging homobinuclear complexes (Cp2MS)2 (1,M=Zr; 2,M=Hf) and a novel organohafnium complex Cp2HfSC(H)NR]2 (3,R=c-C6H11) were respectively obtained from the reactions of Cp2ZrH2 with CS2,RNCS (R=n-Bu,c-C6H11,C6H5,2-C10H7) and Cp2HfH2 with c-C6H11NCS.The structures of the products were identified by elemental analyses,IR,1H and 13C NMR and MS spectra.The crystal structure of 1 was confirmed by X-ray diffraction.The organic products X=CH2 and CH3X(H) (X=S,NR) were identified by GC-MS analyses in the solution. |
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| Keywords: | early-transition-metal hydride earbon disulfied isothlocyanate desulfurization |
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