| 二茂铁甲酰丙酮缩水杨酰肼的d-过渡、ⅡB族及主族金属配合物研究 |
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| 引用本文： | 胡培植,张伦,季立才,吕文进,陈义龙,徐斌富.二茂铁甲酰丙酮缩水杨酰肼的d-过渡、ⅡB族及主族金属配合物研究[J].无机化学学报,1992(2). |
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| 作者姓名： | 胡培植 张伦 季立才 吕文进 陈义龙 徐斌富 |
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| 作者单位： | 武汉大学化学系，武汉大学化学系，武汉大学化学系，武汉大学化学系，武汉大学物理系，武汉大学物理系 武汉 430072，武汉 430072，武汉 430072，武汉 430072，武汉 430072，武汉 430072 |
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| 摘 要： | 将二茂铁甲酰丙酮与水杨酰肼缩合,得含二茂铁基的多齿配体C_5H_5FeC_5H_4C(OH)=CHC(CH_3)=NNHCOC_6H_4OH(简记作FcacacshH_2),该配体分别与d-过渡、ⅡB族及主族金属乙酸盐反应,合成了几个中性固体配合物。经元素分析、红外光谱、紫外—可见光谱、氢核磁共振谱、穆斯堡尔谱、摩尔电导测定对配合物进行表征并研究其性质。
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| 关 键 词： | 二茂铁 四齿配体 金属配合物 |
STUDIES OF d-TRANSITION, II B GROUP AND MAIN GROUP METAL COMPLEXES WITH CONDENSED PRODUCT OF FERROCENOYLACETONE AND SALICYLOYLHYDRAZINE AS LIGAND |
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| Hu Peizhi Zhang Lun Ji Licai Lu Wenjin.STUDIES OF d-TRANSITION, II B GROUP AND MAIN GROUP METAL COMPLEXES WITH CONDENSED PRODUCT OF FERROCENOYLACETONE AND SALICYLOYLHYDRAZINE AS LIGAND[J].Chinese Journal of Inorganic Chemistry,1992(2). |
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| Authors: | Hu Peizhi Zhang Lun Ji Licai Lu Wenjin |
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| Abstract: | A new quatedentate ligand C5H5FeC5H4C(OH) = CHC(CH3) = NNHCOC6H4OH (FcacacshH2) was prepared by the condensation of ferrocenoylacetone and salicyloylhydrazine in methanol and its d-transition, H B group and main group metal complexes (FcacacshHx)yM(M = T1, x=1, y=1; M = Pb, Cd, Ni, x = 0, y=1; M = Zn, Mn, Co, x=1, y=2) were synthesized via the reaction of FcacacshH2 with relevant metal acetate. The IR, UV-Vis, 1HNMR, 57Fe Mossbauer spectra and molar conductance of the ligand and the complexes were studied. |
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| Keywords: | ferrocene quatedentate ligand metal complex |
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