| 二维网状铜(Ⅱ)配合物的合成及晶体结构表征 |
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| 引用本文： | 谢静,陈轩,刘光祥,孙为银.二维网状铜(Ⅱ)配合物的合成及晶体结构表征[J].无机化学学报,2007,23(7):1295-1298. |
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| 作者姓名： | 谢静 陈轩 刘光祥 孙为银 |
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| 作者单位： | 南京大学化学化工学院,配位化学国家重点实验室,配位化学研究所,南京,210093 |
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| 摘 要： | A Cu(Ⅱ) complex Cu(L)1.5(OSO3)]·3H2O (1) L=1,4-bis(imidazol-1-yl)benzene] was synthesized by reaction of ligand L with CuSO4·5H2O using solvothermal method and its structure was determined by X-ray crystal structure analysis. The structure indicates that the complex crystallizes in triclinic, space group P1 with a=0.948 8(2), b=1.078 5(2), c=1.108 4(2) nm, α=74.820(2), β=81.331(2), γ=72.638(2)°, V=1.041 5(3) nm3, Z=2, Dcalc=1.687 g·cm-3, F(000)=544, μ=1.205 cm-1, the final R=0.062 3 and wR=0.132 8. The Cu(Ⅱ) atom has distorted square-pyramidal environment with a N3O2 donor set. Each L ligand links two Cu(Ⅱ) atoms using its imidazole groups to form an infinite one-dimensional (1D) ladder-like chain, which further linked by SO42- to form a two-dimensional (2D) network structure. The 2D sheets are further connected by C-H…O hydrogen bonds to give a three-dimensional (3D) structure. CCDC: 650388.
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| 关 键 词： | 晶体结构 铜(Ⅱ)配合物 合成 |
| 文章编号： | 1001-4861（2007）07-1295-04 |
| 修稿时间： | 2007-05-292007-06-05 |
Synthesis and Crystal Structure of Cu(Ⅱ) Complex with Two-dimensional Network Structure |
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| XIE Jing,CHEN Xuan,LIU Guang-Xiang and SUN Wei-Yin.Synthesis and Crystal Structure of Cu(Ⅱ) Complex with Two-dimensional Network Structure[J].Chinese Journal of Inorganic Chemistry,2007,23(7):1295-1298. |
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| Authors: | XIE Jing CHEN Xuan LIU Guang-Xiang and SUN Wei-Yin |
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| Institution: | School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 and School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 |
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| Abstract: | A Cu(Ⅱ) complex Cu(L)1.5(OSO3)]· 3H2O (1) L=1,4-bis(imidazol-1-yl)benzene] was synthesized by reaction analysis. The structure indicates that the complex crystallizes in triclinic, space group P(1) with a=0.948 8 (2), b=F(000)=544,μ=1.205 cm-1, the final R=0.062 3 and wR=0.132 8. The Cu(Ⅱ) atom has distorted square-pyramidal environment with a N3O2 donor set. Each L ligand links two Cu(Ⅱ) atoms using its imidazole groups to form an infinite one-dimensional (1D) ladder-like chain, which further linked by SO42- to form a two-dimensional (2D)(3D) structure. CCDC: 650388. |
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| Keywords: | crystal structure synthesis |
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