| D,L-1,2,2-三甲基环戊烷-1,3-二胺硝酸镍配合物的合成、结构及其和手性D-(+)-1,2,2-三甲基环戊烷-1,3-二胺氯化镍配合物的对比分析 |
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| 引用本文： | 黄伟,周云曙,李卉卉,钱惠芬,苟少华.D,L-1,2,2-三甲基环戊烷-1,3-二胺硝酸镍配合物的合成、结构及其和手性D-(+)-1,2,2-三甲基环戊烷-1,3-二胺氯化镍配合物的对比分析[J].无机化学学报,2004,20(2). |
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| 作者姓名： | 黄伟 周云曙 李卉卉 钱惠芬 苟少华 |
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| 作者单位： | 1. 南京大学配位化学国家重点实验室,南京,210093
2. 南京工业大学理学院,南京,210009 |
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| 基金项目： | 国家自然科学基金青年基金资助项目(No.20301009)，国家自然科学基金资助项目(No.20271026)，江苏省自然科学基金资助项目(No.BK2001031)。 |
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| 摘 要： | 0IntroductionAsweknow,camphoricderivativespossessingtwochiralcarbonatomsintheirmoleculesoccupyalargebranchoforganiccompoundsandhavebeenusedwidelyinorganicsynthesis.D鄄,L鄄andD,L鄄1,2,2鄄trimethylcyclopentane鄄1,3鄄diaminesareveryusefulintermediatesinorgan
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| 关 键 词： | D L-1 2 2-三甲基环戊烷-1 3-二胺 镍配合物 晶体结构 氢键相互作用 |
Synthesis and Crystal Structure of a Nickel(Ⅱ) Complex [Ni(La)2](NO3)2 (La=D,L-1,2,2-trimethylcyclopentane-1,3-diamine) and Its Comparison with Chiral Complex [Ni(Lb)2]Cl2·2H2O (Lb=D-(+)-1,2,2-trimethylcyclopentane-1,3-diamine) |
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| HUANG Wei,ZHOU Yun-Shu LI Hui-HuiQIAN Hui-FenGOU Shao-Hua.Synthesis and Crystal Structure of a Nickel(Ⅱ) Complex [Ni(La)2](NO3)2 (La=D,L-1,2,2-trimethylcyclopentane-1,3-diamine) and Its Comparison with Chiral Complex [Ni(Lb)2]Cl2·2H2O (Lb=D-(+)-1,2,2-trimethylcyclopentane-1,3-diamine)[J].Chinese Journal of Inorganic Chemistry,2004,20(2). |
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| Authors: | HUANG Wei ZHOU Yun-Shu LI Hui-HuiQIAN Hui-FenGOU Shao-Hua |
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| Institution: | HUANG Wei*,1ZHOU Yun-Shu1 LI Hui-Hui1QIAN Hui-Fen2GOU Shao-Hua*,1 |
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| Abstract: | A nickel(Ⅱ)complex Ni(La)2](NO3)2(1)with bidentate racemic 1,2,2-trimethylcylopentane-1,3-diamine ligand has been synthesized and characterized by IR,EA,ES-MS,and its X-ray diffraction study reveals that the nickel(Ⅱ) center is tetra-coordinated by one D-and one L-diamine ligands,and t three-dimensional Hydrogen-bond-sustained network is formed in the solid state by means of the eight-membered N-H…O hydrogen bond cycle.This compound also supplies a good comparison to the chiral complexNi(Lb)2]Cl2·2H2O(2)(Lb=D-(+)-1,2,2-trimethylcyclopentane-1,3-diamine).CCDC:218122 |
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| Keywords: | D L-1 2 2-trimethylcyclopentane-1 3-diamine nickel(Ⅱ) complex crystal structure hydrogen bonding interactions |
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