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碳螺旋纤维/MnO2复合材料的电化学性能
引用本文:朱亚波,唐国霞,王涛,冯培忠,陶雪钰.碳螺旋纤维/MnO2复合材料的电化学性能[J].无机化学学报,2016,32(8):1353-1357.
作者姓名:朱亚波  唐国霞  王涛  冯培忠  陶雪钰
作者单位:中国矿业大学材料科学与工程学院, 徐州 221116,中国矿业大学材料科学与工程学院, 徐州 221116,中国矿业大学材料科学与工程学院, 徐州 221116,中国矿业大学材料科学与工程学院, 徐州 221116,中国矿业大学材料科学与工程学院, 徐州 221116
基金项目:国家自然科学基金(No.11364013);广西矿冶与环境科学实验中心项目(No.KH2012YB002)资助。
摘    要:利用电泳沉积法(EPD)制备碳螺旋纤维基MnO_2@CMC复合材料,采用电子扫描电镜、拉曼光谱(Raman)、X射线光电子能谱(XPS)对其形貌和结构进行表征并测试其电容性能,结果显示:当电位差扫描速率为5 m V·s-1时,充放电容量较高,可达115F·g-1,在0.2 A·g-1的扫描电流下,循环200圈后电容量为96.7 F·g-1,为起始电容量的89.5%,表现出良好的电容保持率和循环稳定性。

关 键 词:碳螺旋纤维  MnO2  电泳沉积法  电容
收稿时间:2016/1/14 0:00:00
修稿时间:5/9/2016 12:00:00 AM

Electrochemical Property of Carbon Micro-coils/MnO2 Composites
ZHU Ya-Bo,TANG Guo-Xi,WANG Tao,FENG Pei-Zhong and TAO Xue-Yu.Electrochemical Property of Carbon Micro-coils/MnO2 Composites[J].Chinese Journal of Inorganic Chemistry,2016,32(8):1353-1357.
Authors:ZHU Ya-Bo  TANG Guo-Xi  WANG Tao  FENG Pei-Zhong and TAO Xue-Yu
Institution:School of Material Sciences and Engineering, China University of Ming and Technology, Xuzhou, Jiangsu 221116, China,School of Material Sciences and Engineering, China University of Ming and Technology, Xuzhou, Jiangsu 221116, China,School of Material Sciences and Engineering, China University of Ming and Technology, Xuzhou, Jiangsu 221116, China,School of Material Sciences and Engineering, China University of Ming and Technology, Xuzhou, Jiangsu 221116, China and School of Material Sciences and Engineering, China University of Ming and Technology, Xuzhou, Jiangsu 221116, China
Abstract:In this study, Carbon microcoils (CMCs) have been coated by MnO2 using an electrophoresis deposition (EPD) method. The morphology and structure of the composites are characterized by SEM, Raman and XPS, respectively, and their electrochemical properties are also investigated. The experimental results show a specific capacitance of 115 F·g-1 at a scan rate of 5 mV·s-1. Moreover, it retains 96.7 F·g-1 (89.5%) at current density of 0.2 A·g-1 after 200 cycles, which illustrates its good cycling stability.
Keywords:carbon micro-coils  MnO2  electrophoresis deposition  capacitance
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