| 金(Ⅲ)与杯[4]乙酯合钠(Ⅰ)超分子化合物: [Na(C60H80O12)]+[Au(SCN)4]-的合成、结构及性能 |
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| 引用本文： | 付勇,徐琰,宋毛平,吴养洁.金(Ⅲ)与杯[4]乙酯合钠(Ⅰ)超分子化合物: [Na(C60H80O12)]+[Au(SCN)4]-的合成、结构及性能[J].无机化学学报,2005,21(3):379-382. |
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| 作者姓名： | 付勇 徐琰 宋毛平 吴养洁 |
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| 作者单位： | 郑州大学化学系,郑州,450052 |
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| 基金项目： | 国家自然科学基金资助项目(No.20171040),郑州大学青年骨干教师基金资助项目. |
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| 摘 要： | A novel super molecule Na(C60H80O12)]+Au(SCN)4]- was obtained by extraction of calix4] arene (L) for an aqueous solution containing AuCl4]-, and NaCl into CH2Cl2. The crystal structure and properties of the title super molecule were characterized by single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragonal system with space group P4/n and the unit cell parameters were as follows: a=2.880 8(18) nm, b=2.880 8(18) nm, c=2.292 4(5) nm, and final R indices I>2σ(I)]: R1=0.048 5, wR2=0.106 1. CCDC: 243229.
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| 关 键 词： | 杯[4]芳烃 金(Ⅲ) 超分子化合物 合成 晶体结构 |
| 文章编号： | 1001-4861(2005)03-0379-04 |
| 收稿时间： | 2004/7/12 0:00:00 |
| 修稿时间： | 2004年7月12日 |
Synthesis, Crystal Structure and Characterization of a Novel Super Molecule [Na(C60H80O12)]+[Au(SCN)4] |
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| FU Yong,XU Yan,SONG Mao-Ping and WU Yang-Jie.Synthesis, Crystal Structure and Characterization of a Novel Super Molecule [Na(C60H80O12)]+[Au(SCN)4][J].Chinese Journal of Inorganic Chemistry,2005,21(3):379-382. |
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| Authors: | FU Yong XU Yan SONG Mao-Ping and WU Yang-Jie |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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