| 二维网状Pd(Ⅱ)配合物的合成、晶体结构及电化学性质(英文) |
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| 引用本文： | 刘 瑕,刘金明,孙亚光,高恩君,熊 刚,郭美妍.二维网状Pd(Ⅱ)配合物的合成、晶体结构及电化学性质(英文)[J].无机化学学报,2010,26(11):2109-2112. |
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| 作者姓名： | 刘 瑕 刘金明 孙亚光 高恩君 熊 刚 郭美妍 |
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| 作者单位： | 沈阳化工学院应用化学学院,沈阳,110142 |
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| 基金项目： | 沈阳化工学院青年科研启动基金 |
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| 摘 要： | A novel palladium(Ⅱ) complex Pd(H2bpdc)Ala]Cl·3H2O (where H2bpdc is 2,2′-bipyridine-3,3′-dicar- boxylic acid and Ala is L-alanine) has been synthesized and characterized by IR spectra and elemental analysis. The crystal structure of the complex has been determined by single-crystal X-ray diffraction analysis. It crystallizes in triclinic system, space group P1 with a=0.685 5(2) nm, b=0.988 4(4) nm, c=1.349 6(4) nm, α=98.375(8)°, β= 97.900(15)°, γ=90.118(15)°, V=0.895 9(5) nm3, Z=2. In the molecule, Pd(Ⅱ) atom is four-coordinated and located at the centre of a planar quadrangle. The complex is assembled via intramolecular π-π stacking interactions and hydrogen bonds, which forms 2D network. The cyclic voltammetric behavior of the complex was also investigated.
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| 关 键 词： | 钯(Ⅱ)配合物 2，2′-联吡啶-3，3′-二羧酸 晶体结构 电化学性质 |
Synthesis,Crystal Structure and Electrochemical Properties of 2D Network Palladium(Ⅱ)Complex |
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| LIU Xi,LIU Jin-Ming,SUN Ya-Guang,GAO En-Jun,XIONG Gang and GUO Mei-Yan.Synthesis,Crystal Structure and Electrochemical Properties of 2D Network Palladium(Ⅱ)Complex[J].Chinese Journal of Inorganic Chemistry,2010,26(11):2109-2112. |
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| Authors: | LIU Xi LIU Jin-Ming SUN Ya-Guang GAO En-Jun XIONG Gang and GUO Mei-Yan |
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| Institution: | Faculty of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142,Faculty of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142,Faculty of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142,Faculty of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142,Faculty of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142 and Faculty of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142 |
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| Abstract: | A novel palladium(Ⅱ)complexPd(H2bpdc)Ala]C1-3H2O(where H2bpdc is 2,2'-bipyridine-3,3'-dicarboxylic acid and Ala is L-alanine)has been synthesized and characterized by IR spectra and elemental analysis.The crystal structure of the complex has been determined by single-crystal X-ray diffraction analysis.It crystallizes in triclinic system,space group P()1 with a=0.685 5(2)nm,b=0.988 4(4)nm,c=1.349 6(4)nm,a=98.375(8)°,β=97.900(15)°,γ=90.118(15)°,V=0.895 9(5)nm3,Z=2.In the molecule,Pd(Ⅱ)atom is four-coordinated and located at the centre of a planar quadrangle.The complex is assembled via intramolecular π-π stacking interactions and hydrogen bonds,which forms 2D network.The cyclic voltammetric behavior of the complex was also investigated.CCDC:792221. |
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| Keywords: | palladium(Ⅱ)complex 2 2'-bipyridine-3 3'-dicarboxylic acid crystal structure electrochemical propert |
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