含硫镍金属镍配合物[Ni(C13H7Br2NOS)2(DMF)]·(C3H7O)的合成与晶体结构 |
| |
引用本文: | 夏金虹,刘 峥,金黎霞.含硫镍金属镍配合物[Ni(C13H7Br2NOS)2(DMF)]·(C3H7O)的合成与晶体结构[J].无机化学学报,2008,24(5):823-826. |
| |
作者姓名: | 夏金虹 刘 峥 金黎霞 |
| |
作者单位: | 1. 桂林电子科技大学,电子工程学院,桂林,541004 2. 桂林工学院,材料与化学工程系,桂林,541004 |
| |
基金项目: | 广西教育厅学科软环境建设基金 |
| |
摘 要: | The complex, Ni(C13H7Br2NOS)2(DMF)]·(C3H7O) (DMF=N,N′-dimethylformamide), was synthesized and characterized by the element analysis, IR and X-ray diffraction single crystal structure determination. The title complex crystallizes in monoclinic system, space group P21/n, with a=8.297 6(15) nm, b=12.866(2) nm, c=31.889(3) nm, β=95.024(2)°, and V=3 391.3(9) nm3, Z=4, R=0.075 2, wR=0.176 8. The nickel iron is six-coordinated by three O atoms, two N atoms, one S from the Schiff base and one O atom from DMF ligand, forming a octahedron coordination geometry. Schiff bases are bridged by the two S atoms. The molecules in the crystal are linked through intermolecular Br…Br, C-H…O, S…Br interactions. Its electrochemical property is reported. CCDC: 675768.
|
关 键 词: | 席夫碱 镍(Ⅱ)配合物 晶体结构 电化学性质 热重分析 |
文章编号: | 1001-4861(2008)05-0823-04 |
修稿时间: | 2007年8月27日 |
本文献已被 万方数据 等数据库收录! |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|