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Co-Fe普鲁士蓝类配合物纳米颗粒的微乳液法制备与表征
引用本文:方建,杜贤龙,吕辉鸿,郭丹,赵继华,沈伟国.Co-Fe普鲁士蓝类配合物纳米颗粒的微乳液法制备与表征[J].无机化学学报,2007,23(5):923-927.
作者姓名:方建  杜贤龙  吕辉鸿  郭丹  赵继华  沈伟国
作者单位:1. 兰州大学化学化工学院,兰州,730000
2. 华东理工大学化学学院,上海,200237
摘    要:Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio (w), the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy (TEM), field emission scan electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and infrared spectroscopy (IR).

关 键 词:微乳液    Triton  X-100    普鲁士蓝类配合物    纳米颗粒
文章编号:1001-4861(2007)05-0923-05
修稿时间:2006-12-29

Synthesis and Characterization of Cobalt-iron Prussian Blue Analogue Nanoparticles by Microemulsion
FANG Jian,DU Xian-Long,LU Hui-Hong,GUO Dan,ZHAO Ji-Hua and SHEN Wei-Guo.Synthesis and Characterization of Cobalt-iron Prussian Blue Analogue Nanoparticles by Microemulsion[J].Chinese Journal of Inorganic Chemistry,2007,23(5):923-927.
Authors:FANG Jian  DU Xian-Long  LU Hui-Hong  GUO Dan  ZHAO Ji-Hua and SHEN Wei-Guo
Institution:Department of Chemistry, Lanzhou University, Lanzhou 730000,Department of Chemistry, Lanzhou University, Lanzhou 730000,Department of Chemistry, Lanzhou University, Lanzhou 730000,Department of Chemistry, Lanzhou University, Lanzhou 730000,Department of Chemistry, Lanzhou University, Lanzhou 730000 and Department of Chemistry, East China University of Science and Technology, Shanghai 200237
Abstract:Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio (w), the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy (TEM), field emission scan electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and infrared spectroscopy (IR).
Keywords:microemulsion  Triton X-100  Prussian blue analogues  nanoparticle
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