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自激活白光发射Ba2TiP2O9发光材料的发光特性
引用本文:刘春波,车广波.自激活白光发射Ba2TiP2O9发光材料的发光特性[J].无机化学学报,2006,22(3):503-506.
作者姓名:刘春波  车广波
作者单位:吉林师范大学化学学院,四平,136000
摘    要:The Ba2TiP2O9 phosphor was synthesized via the conventional high-temperature solid-state method. The Ba2TiP2O9 phosphor showed high luminance white-light emitting when excited under 254 nm radiation. Furthermore, obvious long-lasting phosphorescence could be observed when the UV excitation source had been removed. XRD and photoluminescence (PL) spectra as well as the luminance decay were used to characterize the synthesized phosphor. The results of XRD indicated that the products obtained under 1 100 ℃ for 3 h had a good crystallization. Both the PL spectra and luminance decay measurement revealed that this kind of phosphors was a new kind of white-light-emitting phosphor. The thermoluminescence properties have also been investigated. The energy level of the 352 K and 493 K TL peaks have also been calculated and found that their energy level values were 0.35 eV and 1.08 eV, respectively. The 352 K TL peak is responsible for the origin of the long-lasting phosphorescence.

关 键 词:发光材料    磷酸盐    钛离子    白光    余辉
文章编号:1001-4861(2006)03-0503-04
收稿时间:2005-07-05
修稿时间:2005-12-07

Luminescent Properties of the Self-activated White-light Emitting Phosphor Ba2TiP2O9
LIU Chun-Bo and CHE Guang-Bo.Luminescent Properties of the Self-activated White-light Emitting Phosphor Ba2TiP2O9[J].Chinese Journal of Inorganic Chemistry,2006,22(3):503-506.
Authors:LIU Chun-Bo and CHE Guang-Bo
Institution:Department of Chemistry, Jilin Normal University, Siping, Jilin 136000 and Department of Chemistry, Jilin Normal University, Siping, Jilin 136000
Abstract:
Keywords:phosphor  phosphate  titanium ions  white-light-emitting  afterglow
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