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新配合物[Cd(H2O)2(phen)2](PA)2的制备及晶体结构
引用本文:李大光,傅维勤,游效曾,Wei Chen.新配合物[Cd(H2O)2(phen)2](PA)2的制备及晶体结构[J].无机化学学报,2002,18(2):209-213.
作者姓名:李大光  傅维勤  游效曾  Wei Chen
作者单位:1. 广东工业大学轻工化工学院,广州,510090;南京大学配位化学研究所,南京,210093
2. 广东工业大学轻工化工学院,广州,510090
3. 南京大学配位化学研究所,南京,210093
4. 马来亚大学化学系,吉隆坡,59100,马来西亚
基金项目:国家自然科学基金资助项目(No.29631040)
摘    要:The new compound was prepared by the reaction of Cd(ClO4)2·6H2O,1,10-phenanthroline (phen)and picric acid (HPA)(ratio 1∶3∶2) in methanol-aqueous solution refluxing for 4 hours. The crystals used for X-ray analysis was obtained by slow evaporation of the solution at room temperature. The crystal compound is in triclinic with space group with a=1.1363(4)nm,b=1.2593(2)nm,c=1.3972(4)nm,α=93.97(2)?,β=100.84(3)?,γ=106.29(2)?,Z=2,V=1.8690(9)nm3,Dc=1.715g·cm-3, μ(MoKα)=0.677mm-1,F(000)=972,R=0.0907,wR=0.2240. In the complex, the Cd(Ⅱ) cation is octahedrally coordinated to two 1,10-phenanthroline ligands and two water molecules in cis disposition. As outer sphere, picrate anions are combined with inner by hydrogen bond and static electricity interaction.

关 键 词:Cd(Ⅱ)配合物  二氮杂菲  苦味酸盐  晶体结构
修稿时间:2001年6月27日

Synthesis and Crystal Structure of the New Complex [Cd(H2O)2(phen)2](PA)2
LI Da-Guang,FU Wei-Qin,YOU Xiao-Zeng and Wei Chen.Synthesis and Crystal Structure of the New Complex [Cd(H2O)2(phen)2](PA)2[J].Chinese Journal of Inorganic Chemistry,2002,18(2):209-213.
Authors:LI Da-Guang  FU Wei-Qin  YOU Xiao-Zeng and Wei Chen
Institution:Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510090;Coordination Chemistry Institute, Nanjing University, Nanjing 210093,Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510090,Coordination Chemistry Institute, Nanjing University, Nanjing 210093 and Department of Chemistry, University of Malaya, Kuala Lumpur 59100,Malaysia
Abstract:
Keywords:Cd ?  complex  1  10  phenanthroline  picrate  crystal structure
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