| 两个含铁、钴、硫金属异核羰基取代簇合物的合成及结构 |
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| 引用本文： | 冶杰慧,索全伶,王晓玲,王一兵,韩利民,竺宁,郑红娜.两个含铁、钴、硫金属异核羰基取代簇合物的合成及结构[J].无机化学学报,2005,21(4):523-526. |
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| 作者姓名： | 冶杰慧 索全伶 王晓玲 王一兵 韩利民 竺宁 郑红娜 |
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| 作者单位： | 1. 内蒙古工业大学化工学院,呼和浩特,010062
2. 西南民族大学,成都,610041 |
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| 基金项目： | 留学回国人员启动基金(No.教外司留,2001-345)，内蒙古自然科学基金(No.200208020113)，内蒙古人才基金，内蒙古工业大学校基金资助项目。 |
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| 摘 要： | Two novel substituted derivatives ( μ3-S)( μ-H)Fe2Co(CO)7Ln (n=2, L=AsPh3 (3) n=1, L=dppm (4)) have been synthesized and characterized by IR, 1H NMR, 31P NMR, MS and X-ray crystallography . The cluster 4 crystallizes in monoclinic space group C2/c, with a=1.589 1(7), b=1.814 9(8), c=2.277 8(11) nm, β=96.861(8), V=6.522(5) nm3, Z=8, Dc=1.552 g·cm-3, F(000)=3 094, μ=12.95 cm-1. Final R indices i>2σ(I)]: R1=0.054 3, wR2=0.101 1. The cyclic voltammetric behavior for the parent cluster 1 and its substituted derivatives were investigated, the results show that the order of σ-donator ability is CO < PPh3 < AsPh3 < dppm. CCDC: 221867.
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| 关 键 词： | Fe2Co簇合物 取代衍生物 晶体结构 电化学性质 |
| 文章编号： | 1001-4861(2005)04-0523-04 |
| 收稿时间： | 7/5/2004 12:00:00 AM |
| 修稿时间： | 2004年7月5日 |
Synthesis and Crystal Structure of Two Heterometallic Carbonyl Substituted Clusters with Fe, Co and S atoms |
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| YE Jie-Hui,SUO Quan-Ling,WANG Xiao-Ling,WANG Yi-Bing,HAN Li-Min,ZHU Ning and ZHENG Hong-Na.Synthesis and Crystal Structure of Two Heterometallic Carbonyl Substituted Clusters with Fe, Co and S atoms[J].Chinese Journal of Inorganic Chemistry,2005,21(4):523-526. |
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| Authors: | YE Jie-Hui SUO Quan-Ling WANG Xiao-Ling WANG Yi-Bing HAN Li-Min ZHU Ning and ZHENG Hong-Na |
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| Institution: | Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010062,Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010062,Southwest University for Nationalities, Chengdu 610041,Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010062,Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010062,Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010062 and Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010062 |
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| Abstract: | |
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| Keywords: | Fe-Co cluster substitution derivative crystal structure electrochemical property |
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