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Cu(Ⅱ)-2′-(2-噻吩亚甲基)水杨酰腙Schiff碱配合物的合成、表征、晶体结构及抑菌活性研究
引用本文:杨健国,潘富友,李钧敏.Cu(Ⅱ)-2′-(2-噻吩亚甲基)水杨酰腙Schiff碱配合物的合成、表征、晶体结构及抑菌活性研究[J].无机化学学报,2005,21(10):1593-1596.
作者姓名:杨健国  潘富友  李钧敏
作者单位:1. 台州学院设备管理处,台州,317000
2. 台州学院生命科学与医药化工学院,台州,317000
基金项目:浙江省自然科学基金资助项目(No.M203115)和浙江省教育厅科研资助项目(No.20050057).
摘    要:In ethanol, the copper(Ⅱ) complex with the 2′-(2-thienylidene)-h ydroxybenzoylhydrazide, Cu(C12H10N2O2S)2, was synthesized, and it′s structure was characterized by IR, UV and elemental analysis. The single crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group C2/c with cell constants, a=2.273 6(4) nm, b=0.592 12(9) nm, c=1.828 1(3) nm, β=109.735(5)°, V=2.316 4(7) nm3, Z=4, μ=1.164 mm-1, Dc=1.595 g·cm-3, F(000)=1 140, R=0.048 6, wR=0.101 6. In the compound copper(Ⅱ) atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. Their biological activities have been measused. The results show that the anti-bacterial activity of the coordination compound is much better that of the ligand. CCDC: 272938.

关 键 词:铜配合物    2′-(2-噻吩亚甲基)水杨酰腙    晶体结构    抑菌活性
文章编号:1001-4861(2005)10-1593-04
收稿时间:3/6/2005 12:00:00 AM
修稿时间:2005-06-30

Synthesis, Characterization, Crystal Structure and Antibacterial Activities of Copper(Ⅱ) Complex with 2'-(2-Thienylidene)-Hydroxybenzoylhydrazide
YANG Jian-Guo,PAN Fu-You and LI Jun-Ming.Synthesis, Characterization, Crystal Structure and Antibacterial Activities of Copper(Ⅱ) Complex with 2''''-(2-Thienylidene)-Hydroxybenzoylhydrazide[J].Chinese Journal of Inorganic Chemistry,2005,21(10):1593-1596.
Authors:YANG Jian-Guo  PAN Fu-You and LI Jun-Ming
Institution:Office of Assets Administration, Taizhou University, Taizhou 317000,Department of Chemistry, Taizhou University, Taizhou 317000 and Department of Chemistry, Taizhou University, Taizhou 317000
Abstract:
Keywords:
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