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钇离子掺杂对二氧化钛纳米薄膜光诱导超亲水性能的影响及其机理
引用本文:曾人杰,庞 起,林仲华,龙翔云,方智敏.钇离子掺杂对二氧化钛纳米薄膜光诱导超亲水性能的影响及其机理[J].无机化学学报,2003,19(7):678-684.
作者姓名:曾人杰  庞 起  林仲华  龙翔云  方智敏
作者单位:1. 厦门大学化学化工学院,固体表面物理化学国家重点实验室,厦门,361005
2. 厦门大学化学化工学院,固体表面物理化学国家重点实验室,厦门,361005;广西大学化学化工学院,南宁,530004
3. 广西大学化学化工学院,南宁,530004
摘    要:用溶胶-凝胶法和浸渍-提拉法工艺,在玻璃表面上制备了均匀、透明的钇离子(Y3+)掺杂二氧化钛纳米薄膜。用XRD分析了样品的晶相及其与热处理温度的关系,用X射线光电子能谱(XPS)分析了薄膜表面氧的状态,用可见光吸收光谱分析了涂膜层数对透光率的影响,用接触角仪测定了其亲水性。研究了Y3+掺杂本身和具体的掺杂量、光照强度和时间对薄膜亲水性的影响。研究结果表明,掺杂Y3+的二氧化钛纳米薄膜,在物质的量分数x(Y3+/Ti4+)=1.5%时,经紫外光照30min或自然光照1h后,与水的接触角小于5°,表现出超亲水性;与纯二氧化钛纳米薄膜相比,其超亲水性对光诱导更为敏感;在有实用意义的超亲水性的稳定方面也有明显的改善;这应部分地与固体化学所描述的Y3+掺杂所造成固定、额外并且是高浓度的氧空位有关。

关 键 词:Y3+掺杂  二氧化钛  光诱导超亲水性  固体化学
修稿时间:2002年12月10

Effects of Y3+ Dopant on the Photoinduced Superhydrophilicity of Thin Nanostructured Titania Films and its Mechanism
ZENG Ren-Jie,PANG Qi,LIN Zhong-Hu,LONG Xiang-Yun and FANG Zhi-Min.Effects of Y3+ Dopant on the Photoinduced Superhydrophilicity of Thin Nanostructured Titania Films and its Mechanism[J].Chinese Journal of Inorganic Chemistry,2003,19(7):678-684.
Authors:ZENG Ren-Jie  PANG Qi  LIN Zhong-Hu  LONG Xiang-Yun and FANG Zhi-Min
Institution:College of Chemistry and Chemical Engineering, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005,College of Chemistry and Chemical Engineering, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005;College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004,College of Chemistry and Chemical Engineering, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005,College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004 and College of Chemistry and Chemical Engineering, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005
Abstract:Homogeneous and transparent thin nanostructured titania films doped by Y3+ were prepared on glass substrates by sol-gel processing and dip-coating technique. The films were characterized by XRD, XPS and visible absorption spectra. The hydrophilicity of the films was determined by measuring the water contact angles for the films. The effects of Y3+ doping, the quantities of Y3+ dopant, and the intensity and the time of light illumination on hy-drophilicity of the films were studied. The results revealed that the film at a mole percent of x(Y3+/Ti4+)=1.5% had a water contact angle of less than 5° after UV illumination for 30min or sunlight for 1h, showing superhy-drophilicity. The films behaved more sensitive to photoinduction and more significantly stable in superhy-drophilicity, compared with the pure titania ones. This might partly be relative with the fixed, extra and highly concentrated oxygen vacancies resulted from Y3+ doping, the mechanics of which were as described in the solid state chemistry.
Keywords:Y3+ doping  titania  photoinduced superhydrophilicity  solid state chemistry
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