| 以Schiff碱N-丁酰基水杨酰肼为配体的三核镍(Ⅱ)配合物的合成与结构 |
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| 引用本文： | 杨明星,林深,陈丽娟,刘世雄.以Schiff碱N-丁酰基水杨酰肼为配体的三核镍(Ⅱ)配合物的合成与结构[J].无机化学学报,2003,19(4). |
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| 作者姓名： | 杨明星 林深 陈丽娟 刘世雄 |
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| 作者单位： | 1. 福建师范大学化学系,福州,350007
2. 福州大学实验中心,福州,350002 |
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| 基金项目： | 教育部高校骨干教师资助计划，福建省青年科技人才创新基金，福建省自然科学基金 |
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| 摘 要： | The trinuclear nickel (Ⅱ) complex Ni3(C11H11N2O3)2(C5H5N)4 was prepared by the reaction of Ni(OAc)2 @ 4H2Owith N-butylsalicylhydrazide Schiff base ligand and characterized by X-ray crystallography. The crystal belongs totriclinic, Mr=930.91, space group P1 with cell parameters a =9. 8489(2)A, b = 12. 3110(2) A, c = 18. 4035(3) A, α=71.353(2)°, β=76.638(2)°, γ=84.815(2)°, V=2056.72(6)A3, Z=2, Dc=1.503g@cm-3,μ(MoKα) = 1. 417mm-1, F(000) = 964, R = 0. 0317, wR = 0. 0868. A total of 5393 independent reflectionswere collected, of which 4448 reflections with I ≥ 2 σ(I) were observed. There are two centrosymmetrical trin-angle of 180°. The interatomic distances between the nickel atoms on the two sides are 9. 2030(8) A and 9. 1876(9) A for the two molecules, respectively. The central nickel atom adopts an axially elongated octahedral geometrywhereas the nickel atoms on the two sides have square-planar coordination environment. CCDC: 194083.
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| 关 键 词： | Schiff碱 镍配合物 腙 晶体结构 |
Synthesis and Crystal Structure of the Trinuclear Nickel (Ⅱ) Complex with Schiff Base Ligand N-butylsalicylhydrazide |
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| Abstract: | The trinuclear nickel (Ⅱ) complex Ni3(C11H11N2O3)2(C5H5N)4 was prepared by the reaction of Ni(OAc)2 @ 4H2Owith N-butylsalicylhydrazide Schiff base ligand and characterized by X-ray crystallography. The crystal belongs totriclinic, Mr=930.91, space group P1 with cell parameters a =9. 8489(2)A, b = 12. 3110(2) A, c = 18. 4035(3) A, α=71.353(2)°, β=76.638(2)°, γ=84.815(2)°, V=2056.72(6)A3, Z=2, Dc=1.503g@cm-3,μ(MoKα) = 1. 417mm-1, F(000) = 964, R = 0. 0317, wR = 0. 0868. A total of 5393 independent reflectionswere collected, of which 4448 reflections with I ≥ 2 σ(I) were observed. There are two centrosymmetrical trin-angle of 180°. The interatomic distances between the nickel atoms on the two sides are 9. 2030(8) A and 9. 1876(9) A for the two molecules, respectively. The central nickel atom adopts an axially elongated octahedral geometrywhereas the nickel atoms on the two sides have square-planar coordination environment. CCDC: 194083. |
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| Keywords: | Schiff base nickel complex hydrazone crystal structure |
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