| 大环Schiff碱希土配合物的合成及表征 |
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| 引用本文： | 臧焰,王德枌,王国雄,曾成.大环Schiff碱希土配合物的合成及表征[J].无机化学学报,1987,3(1):66-74. |
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| 作者姓名： | 臧焰 王德枌 王国雄 曾成 |
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| 作者单位： | 南京大学配位化学研究所
(臧焰，王德枌，王国雄)，南京大学配位化学研究所(曾成) |
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| 基金项目： | 中国科学院科学基金资助的课题 |
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| 摘 要： | 大环化合物及其配合物的研究近来十分活跃,模板反应是合成新型大环配合物的主要手段。通常采用主族金属元素及过渡金属元素离子作模板,而用Ln~(3+)作模板则较少见。本文用自制的呋喃二甲醛—2,5为原料,以Ln~(3+)为模板,合成并表征了一系列大环配合物。
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| 关 键 词： | 模板反应 希土配合物 大环Schiff碱配合物 |
| 收稿时间： | 1986/5/14 0:00:00 |
SYNTHESIS AND CHARACTERIZATION OF RARE EARTH COMPLEXES WITH SCHIFF BASE LIGANDS |
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| Zang Yan,Wang Defen,Wang Guoxiong and Zeng Cheng.SYNTHESIS AND CHARACTERIZATION OF RARE EARTH COMPLEXES WITH SCHIFF BASE LIGANDS[J].Chinese Journal of Inorganic Chemistry,1987,3(1):66-74. |
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| Authors: | Zang Yan Wang Defen Wang Guoxiong and Zeng Cheng |
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| Institution: | Institute of Coordination Chemistry, Nanjing University,Institute of Coordination Chemistry, Nanjing University,Institute of Coordination Chemistry, Nanjing University and Institute of Coordination Chemistry, Nanjing University |
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| Abstract: | Template reactions have played an important role in the synthesis of macrocyclic ligands and complexes. Commonly, main group or transition metal ions are used as templates. There have been, however, few reports of the use of lanthanides as templating reagents. In this paper, we obtain a new series of macrocyclic complexes from 2,5-diformylfuran (DFF) and diamines by template method using lanthanides as templating reagents. The products are characterized by IR, 1H NMR, etc. |
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| Keywords: | macrocyclic Schiff base complex template reaction rare-earth complex |
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