| 铕－邻菲罗啉－甲基苯甲酸二、三元配合物的NMR研究 |
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| 引用本文： | 杨秋青,李林书.铕－邻菲罗啉－甲基苯甲酸二、三元配合物的NMR研究[J].无机化学学报,1994(1). |
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| 作者姓名： | 杨秋青 李林书 |
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| 作者单位： | 河北师范大学实验中心，河北师范学院化学系 |
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| 摘 要： | 本文报道了希土铕（Ｅｕ３＋）与甲基苯甲酸（包括邻位０－ＭＢＡ．间位ｍ—ＭＢＡ，对位ｐ－ＭＢＡ）及邻菲罗咐（Ｐｈｅｎ）形成的二元和三元固体配合物的制备，对它们进行了元素分析，确定该配合物的组成为：二元：Ｅｕ（ＣＨ３Ｃ６Ｈ５ＣＯＯ）３，三元：Ｅｕ（ｐｈｅｎ）（ＣＨ３Ｃ６Ｈ５ＣＯＯ）３．对上述配合物的结构作了核磁共振氢谱（１ＨＮＭＲ）和碳谱（１３ＣＮＭＲ）的研究，并用红外光谱（ＩＲ）作了进一步确定．
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| 关 键 词： | 铕，邻菲罗啉，甲基苯甲酸，~1HNMR，~（13）CNMR，IR |
NMR STUDES OF BINARY AND TERNARY COMPLEXES FOR Eu WITH 1,10-PHENANTHROLINE AND METHYLBENZOIC ACID |
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| Yang Qiuqing.NMR STUDES OF BINARY AND TERNARY COMPLEXES FOR Eu WITH 1,10-PHENANTHROLINE AND METHYLBENZOIC ACID[J].Chinese Journal of Inorganic Chemistry,1994(1). |
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| Authors: | Yang Qiuqing |
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| Abstract: | inary and ternary solidified complexes of rare earth Bu3+ with methylbenzoic acid (including o-methylbenzoic acid, m-methylbenzoic acid, p-methylbenzoic acid) and1,10-phenanthroline were prepared in this article. Their compositions were confirmed by elemental analysis as: binary Eu(CH3C6H5COO)3, ternary Eu(phen) (CH3C6H5COO)3. Their structures were studied'with 1H, 13CNMR spectra. And, their structures were supported further byIR spectrum. |
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