| 四种苯甲酰丙酮合铜和1，1，1-三氟-3-(2-噻吩基)丙酮合铜的偶氮二吡啶长链配合物的热分析研究 |
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| 引用本文： | 陆振荣,丁元晨,徐颖,李宝龙,张勇.四种苯甲酰丙酮合铜和1，1，1-三氟-3-(2-噻吩基)丙酮合铜的偶氮二吡啶长链配合物的热分析研究[J].无机化学学报,2005,21(2):181-185. |
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| 作者姓名： | 陆振荣 丁元晨 徐颖 李宝龙 张勇 |
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| 作者单位： | 1. 苏州大学分析测试中心,苏州,215006
2. 苏州大学化学化工系,苏州,215006 |
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| 摘 要： | 用热重法(TG)研究了4种苯甲酰丙酮合铜和1，1，1-三氟-3-(2-噻吩基)丙酮合铜的偶氮二吡啶一维长链聚合配位化合物在动态氮气气氛下的热行为，结合元素分析和能谱技术，确定了各步分解的组分，并讨论了其晶体结构与热性质的关系。应用新的非线性等转化率法，并结合其他方法考察了各步分解反应的属性，进行了动力学分析，并试对传统动力学方法的适用性进行了讨论。
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| 关 键 词： | 聚合配位化合物 铜 1，1，1-三氟-3-(2-噻吩基)丙酮 苯甲酰丙酮 偶氮二吡啶 热分析 热分解反应动力学 |
| 文章编号： | 1001-4861(2005)02-0181-05 |
| 收稿时间： | 7/5/2004 12:00:00 AM |
| 修稿时间： | 2004年7月5日 |
TA Study on Four One-Dimensional Chain Copper Complexes with Benzoylacetone or 1,1,1-Trifluoro-3-(2-thenoyl)-acetone Bridged through Azobispyridine Ligands |
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| LU Zhen-Rong,DING Yuan-Chen,XU Ying,LI Bao-Long and ZHANG Yong.TA Study on Four One-Dimensional Chain Copper Complexes with Benzoylacetone or 1,1,1-Trifluoro-3-(2-thenoyl)-acetone Bridged through Azobispyridine Ligands[J].Chinese Journal of Inorganic Chemistry,2005,21(2):181-185. |
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| Authors: | LU Zhen-Rong DING Yuan-Chen XU Ying LI Bao-Long and ZHANG Yong |
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| Institution: | Testing and Analysis Center, Suzhou University, Suzhou 215006,Testing and Analysis Center, Suzhou University, Suzhou 215006,Testing and Analysis Center, Suzhou University, Suzhou 215006,Deperment of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006 and Deperment of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006 |
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| Abstract: | TA study on the four one-dimensional chain copper complexes with benzoylacetone or 1,1,1-tri fluoro-3-(2-thenoyl)-acetone bridged through azobispyridine ligands was carried out in a dynamic nitrogen atmosphere. Supplemented by using both elemental analysis and EDS techniques, their thermal behavior and the composition of their intermediate products were examined and discussed in connection with their crystal structure. Thermal decomposition kinetics was investigated employing a newly proposed non-linear isoconversional method, together with four other kinetic methods. The usability of conventional kinetic method was also discussed. |
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| Keywords: | self-assembly of coordination polymer copper 1 1 1-trifluoro-3-(2-thenoyl)-acetone benzoylacetone azobispyridine TA Thermal decomposition kinetics |
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