| 单氨基取代3∶1不对称酞菁锌的合成及其在有机溶剂中聚集状态的研究 |
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| 引用本文： | 陈伟,段武彪,贺春英,左霞,吴谊群.单氨基取代3∶1不对称酞菁锌的合成及其在有机溶剂中聚集状态的研究[J].无机化学学报,2005,21(12):1880-1884. |
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| 作者姓名： | 陈伟 段武彪 贺春英 左霞 吴谊群 |
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| 作者单位： | 1. 黑龙江大学化学化工与材料学院,哈尔滨,150080;齐齐哈尔大学化学化工学院,齐齐哈尔,161006
2. 黑龙江大学化学化工与材料学院,哈尔滨,150080 |
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| 基金项目： | 黑龙江省教育厅科学技术研究项目（No.10541170）和黑龙江省自然科学基金项（No.B2004-05）. |
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| 摘 要： | Monoamino substituted asymmetrical phthalocyanine zinc(Ⅱ), 2-amino-9,10,16,17,23,24-hexapentyloxy phthalocyanine zinc(Ⅱ), was synthesized by statistical condensation and characterized by elemental analysis, UV-Vis, IR and TOF-MS. The aggregative behavior was studied in DMF, THF and CH2Cl2. The results show that it is not aggregateve in DMF and THF, whereas form dimer in CH2Cl2 at 8 × 10-7～8 × 10-6 mol·L-1. The equilibrium constant for the dimer was calculated at the same time, indicating that the less polar solvent is unfavorable for the presence of the monomer.
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| 关 键 词： | 单氨基 不对称酞菁锌 合成 溶液聚集状态 |
| 文章编号： | 1001-4861(2005)12-1880-05 |
| 收稿时间： | 2005-05-23 |
| 修稿时间： | 8/5/2005 12:00:00 AM |
Synthesis of 3:1 Monoamino Substituted Asymmetrical Phthalocyanine Zinc(Ⅱ) and Aggregative Behavior in Organic Solvents |
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| CHEN Wei,DUAN Wu-Biao,HE Chun-Ying,ZUO Xia and WU Yi-Qun.Synthesis of 3:1 Monoamino Substituted Asymmetrical Phthalocyanine Zinc(Ⅱ) and Aggregative Behavior in Organic Solvents[J].Chinese Journal of Inorganic Chemistry,2005,21(12):1880-1884. |
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| Authors: | CHEN Wei DUAN Wu-Biao HE Chun-Ying ZUO Xia and WU Yi-Qun |
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| Institution: | College of Chemistry, Chemical Engineering and Material Science, Heilongjiang University, Harbin 150080;College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006,College of Chemistry, Chemical Engineering and Material Science, Heilongjiang University, Harbin 150080,College of Chemistry, Chemical Engineering and Material Science, Heilongjiang University, Harbin 150080,College of Chemistry, Chemical Engineering and Material Science, Heilongjiang University, Harbin 150080 and College of Chemistry, Chemical Engineering and Material Science, Heilongjiang University, Harbin 150080 |
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