| 一维链配位聚合物[Mn(acacen){N(CN)2}]n的合成、结构和性质的研究(英) |
| |
| 引用本文： | 王寿武,周俊慧,李宝龙,张 勇.一维链配位聚合物[Mn(acacen){N(CN)2}]n的合成、结构和性质的研究(英)[J].无机化学学报,2004,20(12):1463-1466. |
| |
| 作者姓名： | 王寿武 周俊慧 李宝龙 张 勇 |
| |
| 作者单位： | 1. 苏州大学化学化工学院,江苏省有机合成重点实验室,苏州,215006;淮海工学院东港学院,连云港,222069
2. 苏州大学化学化工学院,江苏省有机合成重点实验室,苏州,215006 |
| |
| 基金项目： | 江苏省高校自然科学基金(No.03KJB150118)，江苏省有机合成重点实验室开放基金资助项目 |
| |
| 摘 要： | The manganese(Ⅲ) complex Mn(acacen){N(CN)2}]n H2acacen=bis(acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligand μ1,5-N(CN)2]- linking Mn(acacen)] moiety. The magnetic property of the compound (75～300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.
|
| 关 键 词： | 晶体结构 一维链 锰配合物 二氰氨基 |
Synthesis, Structure and Property of One-dimensional Chain Coordination Polymer [Mn(acacen){N(CN)2}]n |
| |
| WANG Shou-Wu,ZHOU Jun-Hui,LI Bao-Long and ZHANG Yong.Synthesis, Structure and Property of One-dimensional Chain Coordination Polymer [Mn(acacen){N(CN)2}]n[J].Chinese Journal of Inorganic Chemistry,2004,20(12):1463-1466. |
| |
| Authors: | WANG Shou-Wu ZHOU Jun-Hui LI Bao-Long and ZHANG Yong |
| |
| Institution: | Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006;Donggang College, Huaihai Institute of Technology, Lianyuangang 222069,Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006,Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006 and Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006 |
| |
| Abstract: | The manganese(II) complex Mn(acacen){N(CN)2}]n H2acacen=bis(acetylaceton e )ethylenediimine] has been synthesized and the structure has been determined. Th e complex forms a one-dimensional chain structure via the bidentate bridge ligan d -linking Mn(acacen)] moiety. The magnetic property of the comp ound (75~300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940. |
| |
| Keywords: | crystal structure one-dimensional chain manganese complex dicyanamide |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
