| 含轴手性磺酸配体的镉配合物(英) |
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| 引用本文： | 唐云志,周挺.含轴手性磺酸配体的镉配合物(英)[J].无机化学学报,2005,21(9):1435-1436. |
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| 作者姓名： | 唐云志 周挺 |
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| 作者单位： | 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 973项目(No.G2000077500)资助项目 |
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| 摘 要： | The crystal structure of Cd(BDA)(phen)2(H2O)](H2O)2 (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate, phen=1,10-phenanthroline)consists of a cadmium center whose coordination environment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen ligands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interactions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC: 277921.
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| 关 键 词： | 晶体结构 6，6′-二溴-2，2′-二甲氧基-1，1′-二萘-4，4′-二磺酸 镉 |
| 文章编号： | 1001-4861(2005)09-1435-02 |
| 收稿时间： | 2005-02-15 |
| 修稿时间： | 6/1/2005 12:00:00 AM |
Cd(Ⅱ) Complex with Disulfonate Atropisomeric Ligand |
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| TANG Yun-Zhi and ZHOU Ting.Cd(Ⅱ) Complex with Disulfonate Atropisomeric Ligand[J].Chinese Journal of Inorganic Chemistry,2005,21(9):1435-1436. |
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| Authors: | TANG Yun-Zhi and ZHOU Ting |
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| Institution: | Coordination Chemistry Institute,State Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute,State Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | The crystal structure of Cd(BDA)(phen)2(H2O)](H2O)2 (1) (BDA=6,6'-dibromo-2,2'-dimethoxy-1,1'-binaphthylene-4,4'-disulfonate, phen=1,10-phenanthroline)consists of a cadmium center whose coordination environment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen lig ands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interactions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC: 277921. |
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| Keywords: | crystal structure 6 6'-dibromo-2 2'-dimethoxy-1 1'-binaphthylene-4 4 '-disulfonic acid cadmium |
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