| Ag(Ⅰ)、Pd(Ⅱ)异核金属簇合物的制备和晶体结构研究 |
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| 引用本文： | 司徒粤,黄少斌,张居光.Ag(Ⅰ)、Pd(Ⅱ)异核金属簇合物的制备和晶体结构研究[J].无机化学学报,2003,19(9):983-987. |
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| 作者姓名： | 司徒粤 黄少斌 张居光 |
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| 作者单位： | 华南理工大学应用化学系,广州,510640 |
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| 基金项目： | 国家自然科学基金资助项目(No.20277009)。 |
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| 摘 要： | The complexes of Ag2Pd2(μ-dppm)2(μ-S2CNC4H8)2(μ3-S2CNC4H8)2](SbF6)2·Et2O (1) and AgPd(S2CN C4H8)(μ-dppm)2](SbF6)·H2O (2)were synthesized and their single crystal structures were determined by X-ray diffraction. The complex 1 is monoclinic system, space group P21/c with a=1.14370(3)nm, b=1.39025(4)nm, c=2.93579(8)nm, β=95.173(1)°, V=4.6490(2)nm3, Z=4, Dc=1.716g·cm-3, μ(Mo Kα)=1682cm-1, F(000)=2384, Mr=2401.98, R=0.0662, wR=0.1302. The complex 2 is monoclinic system, space group Cc with a=2.74136(6)nm, b=1.04317(2)nm, c=2.523990(10)nm, β=95.173(1)°, V=4.6490(2)nm3, Z=4, Dc=1.716g·cm-3, μ(Mo Kα)=1682cm-1, F(000)=2384, Mr=2401.98, R=0.0662, wR=0.1302. CCDC: 1, 213613; 2, 213612.
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| 关 键 词： | 双膦 异核金属簇合物 晶体结构 |
| 修稿时间： | 2003年2月26日 |
Synthesis and Crystal Structures of Heterometallic Ag (Ⅰ), Pd (Ⅱ) Complexes |
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| SITU Yue,HUANG Shao-Bin and ZHANG Ju-Guang.Synthesis and Crystal Structures of Heterometallic Ag (Ⅰ), Pd (Ⅱ) Complexes[J].Chinese Journal of Inorganic Chemistry,2003,19(9):983-987. |
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| Authors: | SITU Yue HUANG Shao-Bin and ZHANG Ju-Guang |
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| Institution: | Department of Applied Chemistry, South China University of Technology, Guangzhou 510640,Department of Applied Chemistry, South China University of Technology, Guangzhou 510640 and Department of Applied Chemistry, South China University of Technology, Guangzhou 510640 |
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| Abstract: | |
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| Keywords: | diphosphine heterometallic complex crystal structure |
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