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| 固相反应法合成掺铝的α型氢氧化镍及其电化学性能 | |
| 引用本文： | 许娟,周益明,唐亚文,王青,陆天虹,唐琛明,高效岳,沈涛,忻新泉.固相反应法合成掺铝的α型氢氧化镍及其电化学性能[J].无机化学学报,2003,19(5):535-538. |
| 作者姓名： | 许娟 周益明 唐亚文 王青 陆天虹 唐琛明 高效岳 沈涛 忻新泉 |
| 作者单位： | 1. 南京师范大学化学与环境科学学院,南京,210097 2. 江苏海四达集团有限公司,启东,226200 3. 南京大学配位化学研究所,配位化学国家重点实验室,南京210093 |
| 基金项目： | 江苏省教委自然科学基金资助项目(No.00KJB150005,01KJB150007)，南京师范大学物理化学重点学科基金资助项目(No.121090B501)。 |
| 摘 要： | Ni(OH)2 including 20% Al was synthesized by solid-state reaction. The result of XRD indicated that the sample thus prepared was α-Ni(OH)2， and its size and crystalline form were much poorer than those of the sample prepared by solution-state reaction. TG and DTA curves showed that α-Ni(OH)2 began to decompose at higher temperature than β-Ni(OH)2. The electrochemical behaviors of the sample were studied by cyclic voltammetry and constant current charge-discharge experiment. It was found that the sample by solid-state reaction had more ex-cellent electrode reversibility， higher discharge potential and higher discharge capacity. |
| 关 键 词： | α-Ni(OH)2 固相合成 镍电极 电化学 |
| 修稿时间： | 2002年12月25 |
Solid State Synthesis and Electrochemical Performances of α-Ni (OH)2 including 20% Al |
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| XU Juan,ZHOU Yi-Ming,TANG Ya-Wen,WANG Qing,LU Tian-Hong,TANG Chen-Ming,GAO Xiao-Yue,SHEN Tao and XIN Xin-Quan.Solid State Synthesis and Electrochemical Performances of α-Ni (OH)2 including 20% Al[J].Chinese Journal of Inorganic Chemistry,2003,19(5):535-538. | |
| Authors: | XU Juan ZHOU Yi-Ming TANG Ya-Wen WANG Qing LU Tian-Hong TANG Chen-Ming GAO Xiao-Yue SHEN Tao and XIN Xin-Quan |
| Abstract: | |
| Keywords: | Ni(OH)2solid state synthesisnickel electrodeelectrochemistry |
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